KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
Carbon materials derived from chitosan cellulose cryogel supported zeolite imidazole frameworks for potential supercapacitor application | |
Li, Zehui; Yang, Lan; Cao, Hongbin; Chang, Yu; Tang, Kexin; Cao, Zhiqin; Chang, Junjunl Cao Youpeng; Wang, Wenbo; Gao, Meng; Liu, Chenming; Liu, Dagang; Zhao, He; Zhang, Yi; Li, Mingjie | |
2017-08-01 | |
发表期刊 | Carbohydrate Polymers |
卷号 | 175期号:1页码:223-230 |
产权排序 | 6 |
摘要 | In order to promote sustainable development, green and renewable clean energy technologies continueto be developed to meet the growing demand for energy, such as supercapacitor, fuel cells and lithium-ion battery. It is urgent to develop appropriate nanomaterials for these energy technologies to reducethe volume of the device, improve the efficiency of energy conversion and enlarge the energy storagecapacity. Here, chitosan/cellulose carbon cryogel (CCS/CCL) were designed and synthesized. Through theintroduction of zeolite imidazole frameworks (ZIFs) into the chitosan/cellulose cryogels, the obtainedmaterials showed a microstructure of ZIF-7 (a kind of ZIFs) coated chitosan/cellulose fibers (CS/CL). Aftercarbonizing, the as-prepared carbonized ZIF-7@cellulose cryogel (NC@CCL, NC is carbonized ZIF-7) andcarbonized ZIF-7@chitosan cryogel (NC@CCS) exhibited suitable microspore contents of 34.37% and 30%,respectively, and they both showed an internal resistance lower than 2 . Thereby, NC@CCL and NC@CCSexhibited a high specific capacitance of 150.4 F g−1and 173.1 F g−1, respectively, which were much higherthan those of the original materials. This approach offers a facile method for improving the strength andelectronic conductivity of carbon cryogel derived from nature polymers, and also efficiently inhibits theagglomeration of cryogel during carbonization in high temperature, which opens a novel avenue for thedevelopment of carbon cryogel materials for application in energy conversion systems. |
文章类型 | Article |
DOI | 10.1016/j.carbpol.2017.07.089 |
关键词[WOS] | Chitosan ; Cellulose ; Carbon cryogel ; Zeolite imidazole frame ; works Supercapacitor |
语种 | 英语 |
项目资助者 | National HighTechnology Research ; Development Program of China (863 Pro-gram) (No. 2014AA06A513) ; National Natural Science Foundationof China (No. 51425405, 51608509) ; China Postdoctoral ScienceFoundation Funded Project (2016M590670) |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9820 |
专题 | 仿生智能材料研究组 |
通讯作者 | Liu, Chenming; Li, Mingjie |
作者单位 | 1.中国科学院过程工程研究所 2.清华大学 3.中国科学院大学 4.华北电力大学 5.南京信息工程大学 6.中国科学院青岛生物能源与过程研究所 |
推荐引用方式 GB/T 7714 | Li, Zehui,Yang, Lan,Cao, Hongbin,et al. Carbon materials derived from chitosan cellulose cryogel supported zeolite imidazole frameworks for potential supercapacitor application[J]. Carbohydrate Polymers,2017,175(1):223-230. |
APA | Li, Zehui.,Yang, Lan.,Cao, Hongbin.,Chang, Yu.,Tang, Kexin.,...&Li, Mingjie.(2017).Carbon materials derived from chitosan cellulose cryogel supported zeolite imidazole frameworks for potential supercapacitor application.Carbohydrate Polymers,175(1),223-230. |
MLA | Li, Zehui,et al."Carbon materials derived from chitosan cellulose cryogel supported zeolite imidazole frameworks for potential supercapacitor application".Carbohydrate Polymers 175.1(2017):223-230. |
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