QIBEBT-IR  > 新型能源碳素材料团队
Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage
Wang, Ning1; He, Jianjiang1,2; Tu, Zeyi2,3; Yang, Ze1; Zhao, Fuhua1; Li, Xiaodong1,2; Huang, Changshui1; Wang, Kun1; Jiu, Tonggang1; Yi, Yuanping3; Li, Yuliang3
2017-08-28
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume56Issue:36Pages:10740-10745
AbstractChlorine-substituted graphdiyne (Cl-GDY) is prepared through a Glaser-Hay coupling reaction on the copper foil. Cl-GDY is endowed with a unique pi-conjugated carbon skeleton with expanded pore size in two dimensions, having graphdiyne-like sp- and sp(2)- hybridized carbon atoms. As a result, the transfer tunnels for lithium (Li) ions in the perpendicular direction of the molecular plane are enlarged. Moreover, benefiting from the bottom-to-up fabrication procedure of graphdiyne and the strong chemical tailorability of the alkinyl-contained monomer, the amount of substitutional chlorine atoms with appropriate electronegativity and atom size is high and evenly distributed on the as-prepared carbon framework, which will synergistically stabilize the Li intercalated in the Cl-GDY framework, and thus generate more Li storage sites. Profiting from the above unique structure, Cl-GDY shows remarkable electrochemical properties in lithium ion half-cells.
SubtypeArticle
KeywordCarbon Materials Chlorine Energy Storage Graphdiyne Two-dimensional Materials
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/anie.201704779
WOS KeywordCARBON MATERIALS ; BATTERY ANODE ; GRAPHENE ; ELECTRODES
Indexed BySCI
Language英语
WOS Research AreaChemistry
Funding Organization"Hundred Talents Program" of the Chinese Academy of Sciences ; Frontier Science Research Project of the Chinese Academy of Sciences(QYZDB-SSW-JSC052) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12020200) ; Natural Science Foundation of Shandong Province (China) for Distinguished Young Scholars(JQ201610) ; National Natural Science Foundation of China
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000408267000019
Citation statistics
Cited Times:58[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qibebt.ac.cn/handle/337004/9725
Collection新型能源碳素材料团队
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
3.Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Ning,He, Jianjiang,Tu, Zeyi,et al. Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(36):10740-10745.
APA Wang, Ning.,He, Jianjiang.,Tu, Zeyi.,Yang, Ze.,Zhao, Fuhua.,...&Li, Yuliang.(2017).Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(36),10740-10745.
MLA Wang, Ning,et al."Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.36(2017):10740-10745.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Ning]'s Articles
[He, Jianjiang]'s Articles
[Tu, Zeyi]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Ning]'s Articles
[He, Jianjiang]'s Articles
[Tu, Zeyi]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Ning]'s Articles
[He, Jianjiang]'s Articles
[Tu, Zeyi]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.