Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage

doi:10.1002/anie.201704779

QIBEBT-IR > 碳基材料与能源应用研究组

	Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage
	Wang, Ning 1; He, Jianjiang1,2 ; Tu, Zeyi 2,3; Yang, Ze 1; Zhao, Fuhua1 ; Li, Xiaodong 1,2; Huang, Changshui 1; Wang, Kun 1; Jiu, Tonggang 1; Yi, Yuanping 3; Li, Yuliang 3
	2017-08-28
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷号	56 期号:36 页码:10740-10745
摘要	Chlorine-substituted graphdiyne (Cl-GDY) is prepared through a Glaser-Hay coupling reaction on the copper foil. Cl-GDY is endowed with a unique pi-conjugated carbon skeleton with expanded pore size in two dimensions, having graphdiyne-like sp- and sp(2)- hybridized carbon atoms. As a result, the transfer tunnels for lithium (Li) ions in the perpendicular direction of the molecular plane are enlarged. Moreover, benefiting from the bottom-to-up fabrication procedure of graphdiyne and the strong chemical tailorability of the alkinyl-contained monomer, the amount of substitutional chlorine atoms with appropriate electronegativity and atom size is high and evenly distributed on the as-prepared carbon framework, which will synergistically stabilize the Li intercalated in the Cl-GDY framework, and thus generate more Li storage sites. Profiting from the above unique structure, Cl-GDY shows remarkable electrochemical properties in lithium ion half-cells.
文章类型	Article
关键词	Carbon Materials Chlorine Energy Storage Graphdiyne Two-dimensional Materials
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/anie.201704779
关键词[WOS]	CARBON MATERIALS ; BATTERY ANODE ; GRAPHENE ; ELECTRODES
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	"Hundred Talents Program" of the Chinese Academy of Sciences ; Frontier Science Research Project of the Chinese Academy of Sciences(QYZDB-SSW-JSC052) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12020200) ; Natural Science Foundation of Shandong Province (China) for Distinguished Young Scholars(JQ201610) ; National Natural Science Foundation of China
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000408267000019
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9725
专题	碳基材料与能源应用研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ning,He, Jianjiang,Tu, Zeyi,et al. Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(36):10740-10745.
APA	Wang, Ning.,He, Jianjiang.,Tu, Zeyi.,Yang, Ze.,Zhao, Fuhua.,...&Li, Yuliang.(2017).Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(36),10740-10745.
MLA	Wang, Ning,et al."Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.36(2017):10740-10745.