Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries

doi:10.1021/acsami.6b04355

QIBEBT-IR > 先进界面技术研究组

	Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries
	Zhu, Shaoyin1 ; Wang, Yanqing 1; Jiang, Jicheng 1; Yan, Xiao1 ; Sun, Deye 1; Jin, Yongcheng 1; Nan, Cewen 2; Munakata, Hirokazu 3; Kanamura, Kiyoshi 3
	2016-07-13
发表期刊	ACS APPLIED MATERIALS & INTERFACES
卷号	8 期号:27 页码:17253-17259
摘要	Despite the increased attention devoted to exploring cathode construction based on various nitrogen enriched carbon scaffolds at room temperature, the low temperature behaviors of Li-S cathodes have yet to be studied. Herein, we demonstrate the good low-temperature electrochemical performances of nitrogen-enriched carbon/sulfur composite cathodes. Electrochemical evaluation indicates that a reversible capacity of 368 mAh g(-1) (0.5 C) over 100 cycles is achieved at -20 degrees C. After returning to 25 degrees C, a capacity of 620 mAh g(-1) (0.5 C) is achieved over 350 cycles with a low-capacity attenuation rate (0.071% per cycle) and an initial capacity of 1151 mAh g(-1) (0.1C). This positive electrochemical property was speculated to result from the good surface chemistry of the various amine groups in the nitrogen-enriched carbon materials with enhanced polysulfide immobilization.
文章类型	Article
关键词	Nitrogen-enriched Carbon Low Temperature Polysulfide Immobilization Surface Chemistry Li-s Cathodes
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acsami.6b04355
关键词[WOS]	CATHODE MATERIAL ; SECONDARY BATTERIES ; MESOPOROUS CARBONS ; ENERGY-STORAGE ; DOPED GRAPHENE ; LITHIUM ; COMPOSITE ; CONDENSATION ; ELECTRODES ; MELAMINE
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science
项目资助者	National Natural Science Foundation of China(21503250) ; Chinese Academy of Sciences ; CAS Key Laboratory of Biobased Materials of Qingdao Institute of Bioenergy and Bioprocess Technology
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000379794100029
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8389
专题	先进界面技术研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China 3.Tokyo Metropolitan Univ, Grad Sch Urban Environm Sci, Dept Appl Chem, 1-1 Minami Ohsawa, Hachioji, Tokyo 1920397, Japan
推荐引用方式 GB/T 7714	Zhu, Shaoyin,Wang, Yanqing,Jiang, Jicheng,et al. Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(27):17253-17259.
APA	Zhu, Shaoyin.,Wang, Yanqing.,Jiang, Jicheng.,Yan, Xiao.,Sun, Deye.,...&Kanamura, Kiyoshi.(2016).Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries.ACS APPLIED MATERIALS & INTERFACES,8(27),17253-17259.
MLA	Zhu, Shaoyin,et al."Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries".ACS APPLIED MATERIALS & INTERFACES 8.27(2016):17253-17259.