| Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites | |
Meng, Qiyan1,2; Xin, Hongchuan2; Zhang, Yufei2; Huang, Yan1; Yi, Xianfeng3; Sun, Yuanyuan2 ; Zhong, Shifa2; Li, Xuebing2
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| 2015-11-01 | |
| 发表期刊 | SCIENCE OF ADVANCED MATERIALS
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| 卷号 | 7期号:11页码:2343-2351 |
| 摘要 | The steam-treated ZSM-5 zeolites are characterized by XRD, N-2 sorption, SEM, Al-27 MAS NMR and NH3-TPD techniques. The steaming procedures do not alter textural structures, but generate significant variations in the acidity. The catalytic properties of steam-treated ZSM-5 catalysts in dehydration of ethanol into ethylene are investigated in a fixed bed reactor at 150-350 degrees C and an atmospheric pressure. The decreased total acid sites and increased ratio of weak acid to strong acid after steam treatment may suppress ethylene from secondary reactions, and therefore lead to improved ethylene selectivity at higher temperature. Compared to parent ZSM-5, ZSM-5 treated at 600 degrees C (ZSM-600) shows excellent stability for ethylene production. The reaction conditions (space velocity and ethanol partial pressure) have significant influences on ethanol conversion and ethylene selectivity. |
| 文章类型 | Article |
| 关键词 | Zsm-5 Steam Treatment Ethanol Dehydration Ethylene Acidity |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| DOI | 10.1166/sam.2015.2388 |
| 关键词[WOS] | SOLID ACID CATALYSTS ; HZSM-5 ZEOLITE ; THEORETICAL CALCULATION ; AQUEOUS-ETHANOL ; STATE NMR ; P-31 NMR ; CONVERSION ; H-ZSM-5 ; DEALUMINATION ; METHANOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
| 项目资助者 | Natural Science Foundation of China(21262036) ; Doctoral Fund of Shandong Province(BS2013CL029) ; Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education ; Xinjiang Uyghur Autonomous Region, Xinjiang University(XJDX0908-2012-5) ; Xinjiang Uygur Autonomous Region science and technology plans(201416101) |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| WOS记录号 | WOS:000366295900010 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6839 |
| 专题 | 多相催化转化研究组 |
| 作者单位 | 1.Xinjiang Univ, Coll Chem & Chem Engn, Key Lab Oil & Gas Fine Chem, Minist Educ, Urumqi 830046, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Qiyan,Xin, Hongchuan,Zhang, Yufei,et al. Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites[J]. SCIENCE OF ADVANCED MATERIALS,2015,7(11):2343-2351. |
| APA | Meng, Qiyan.,Xin, Hongchuan.,Zhang, Yufei.,Huang, Yan.,Yi, Xianfeng.,...&Li, Xuebing.(2015).Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites.SCIENCE OF ADVANCED MATERIALS,7(11),2343-2351. |
| MLA | Meng, Qiyan,et al."Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites".SCIENCE OF ADVANCED MATERIALS 7.11(2015):2343-2351. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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