KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
Synthesis and Crystal Structure of a New (6,3)-Connected Ni(II) Coordination Polymer | |
Wang Ai-Dong2; Qiu Jian-Chao3; Guo Feng1; Zhang Xiu-Ling1 | |
2010 | |
发表期刊 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY |
卷号 | 29期号:6页码:982-985 |
摘要 | The coordination polymer [Ni(dpa)(bPP)](n) (H(2)dpa 2,4'-biphenyl-dicarboxylic acid, bpp = 1,3-di(4-pyridyl)propane) was hydrothermally prepared and characterized by single-crystal X-ray diffraction, FTIR spectra, elemental analysis and thermal analysis. The crystal is of triclinic system, space group P (1) over bar with a = 12.516(5), b = 12.943(5), c = 15.130(5) angstrom, alpha = 94.331(5), beta = 91.827(5), gamma = 108.382(5)degrees, C(54)H(44)N(4)Ni(2)O(8), M(r) = 497.18, V = 2315.3(15) angstrom(3), D(c) = 1.426 g/cm(3), F(000) = 1032, mu = 0.875 cm(-1), Z = 2, the final R = 0.0496 and wR = 0.1100 for 5365 reflections with I > 2 sigma(I). X-ray diffraction analysis reveals that the carboxylate group of 2,4'-diphenic acids acting as bridging ligands adopts two coordination modes: bis-mondentate and bidentate chelating. The compound exhibits a two-dimensional (6,3)-connected architecture. |
文章类型 | Article |
关键词 | Coordination Polymer Hydrothermal Synthesis Crystal Structure |
WOS标题词 | Science & Technology ; Physical Sciences |
关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; HYDROTHERMAL SYNTHESES ; CADMIUM(II) COMPLEXES ; MAGNETIC-PROPERTIES ; DIPHENIC ACID ; CHAIN ; STORAGE ; COBALT(II) ; CHEMISTRY ; NETWORKS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Crystallography |
WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
WOS记录号 | WOS:000279582300026 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6748 |
专题 | 育成中心 |
作者单位 | 1.Dezhou Univ, Dept Chem, Dezhou 253023, Peoples R China 2.Huangshan Univ, Dept Chem, Huangshan 245041, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Ai-Dong,Qiu Jian-Chao,Guo Feng,et al. Synthesis and Crystal Structure of a New (6,3)-Connected Ni(II) Coordination Polymer[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2010,29(6):982-985. |
APA | Wang Ai-Dong,Qiu Jian-Chao,Guo Feng,&Zhang Xiu-Ling.(2010).Synthesis and Crystal Structure of a New (6,3)-Connected Ni(II) Coordination Polymer.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,29(6),982-985. |
MLA | Wang Ai-Dong,et al."Synthesis and Crystal Structure of a New (6,3)-Connected Ni(II) Coordination Polymer".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 29.6(2010):982-985. |
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