| Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study | |
| Zhao, Na; Qiu, Li; Wang, Xiao; Li, Jianzhong; Jiang, Yi; Wan, Xiaobo | |
| 2012-11-25 | |
| 发表期刊 | TETRAHEDRON
 |
| 卷号 | 68期号:47页码:9665-9671 |
| 摘要 | Dibenzo[bf][1,5]diazocines, a class of potential building blocks for novel electrochemical actuators, were synthesized via a novel, efficient acid-catalyzed reaction of 2-acylbenzoisocyanate at room temperature. Real-time NMR analysis and the captured intermediate showed the mechanism was an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization. (c) 2012 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.tet.2012.09.050 |
| 关键词[WOS] | ISOCYANATE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| WOS记录号 | WOS:000310402400019 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6388 |
| 专题 | 生物基及仿生高分子材料团队（过去） |
| 作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Na,Qiu, Li,Wang, Xiao,et al. Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study[J]. TETRAHEDRON,2012,68(47):9665-9671. |
| APA | Zhao, Na,Qiu, Li,Wang, Xiao,Li, Jianzhong,Jiang, Yi,&Wan, Xiaobo.(2012).Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study.TETRAHEDRON,68(47),9665-9671. |
| MLA | Zhao, Na,et al."Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study".TETRAHEDRON 68.47(2012):9665-9671. |
| 条目包含的文件 | 下载所有文件 | |||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Trifluoroacetic acid（717KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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