Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study

doi:10.1016/j.tet.2012.09.050

	Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study
	Zhao, Na; Qiu, Li; Wang, Xiao; Li, Jianzhong; Jiang, Yi; Wan, Xiaobo
	2012-11-25
发表期刊	TETRAHEDRON
卷号	68 期号:47 页码:9665-9671
摘要	Dibenzo[bf][1,5]diazocines, a class of potential building blocks for novel electrochemical actuators, were synthesized via a novel, efficient acid-catalyzed reaction of 2-acylbenzoisocyanate at room temperature. Real-time NMR analysis and the captured intermediate showed the mechanism was an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization. (c) 2012 Elsevier Ltd. All rights reserved.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1016/j.tet.2012.09.050
关键词[WOS]	ISOCYANATE
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000310402400019
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6388
专题	生物基及仿生高分子材料团队（过去）
作者单位	Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Na,Qiu, Li,Wang, Xiao,et al. Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study[J]. TETRAHEDRON,2012,68(47):9665-9671.
APA	Zhao, Na,Qiu, Li,Wang, Xiao,Li, Jianzhong,Jiang, Yi,&Wan, Xiaobo.(2012).Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study.TETRAHEDRON,68(47),9665-9671.
MLA	Zhao, Na,et al."Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study".TETRAHEDRON 68.47(2012):9665-9671.

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