Synthesis and characterization of ordered mesoporous carbons CMK-3 produced by tailoring the mesopores of an AlSBA-15hard template synthesized without acid

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	Synthesis and characterization of ordered mesoporous carbons CMK-3 produced by tailoring the mesopores of an AlSBA-15hard template synthesized without acid
	Shi Lei 1; Xu Yan 2,3; Xing Li-shu 2,3; Li Xiang-ping 3; Yang Cheng 3; Lin Sen 3
	2014-12-01
发表期刊	NEW CARBON MATERIALS
卷号	29 期号:6 页码:515-521
摘要	Highly ordered mesoporous carbons (OMCs) designated CMK-3 were synthesized using mesoporous Al-SBA-15 with different textural properties as hard templates and sucrose as a carbon source. Al-SBA-15 is an ordered mesoporous alumina-silica synthesized with a soft template, P123. The effect of the aging temperature for the hard templates on the pore structure of CMK-3 was investigated. X-ray diffraction, N2 adsorption and transmission electron microscopy were used to characterize the pore structures of the hard templates and the resultant CMK-3. Result indicates that CMK-3 with different pore structures can be obtained by tailoring the pore structures of the hard templates bysimply controlling the aging temperature in an acid-free medium. The best CMK-3 possessed a highly-ordered pore structure, and a very high BET surface area (1 688 m(2).g(-1)) and pore volume (0.95 cm(3).g(-1)) when the hard template was aged at 90 degrees C. The microporous character of the CMK-3 was related to the thickness of the mesopore wall of the hard templates. The textural characteristics of the resultant CMK-3 can be improved by simply adjusting the aging temperature in the synthesis of the hard templates to control their mesopore structure.
文章类型	Article
关键词	Ordered Mesporous Cmk-3 Hard Templates Alsba-15 Aging Temperature Controllable Pore Structure
WOS标题词	Science & Technology ; Technology
关键词[WOS]	SILICAS ; ELECTRODE ; SBA-15 ; MICROPOROSITY ; TEMPERATURE ; CATALYST
收录类别	SCI
语种	英语
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000347668400016
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6281
专题	多相催化转化研究组
作者单位	1.Shandong Polytech Univ, Shandong Prov Key Lab Fine Chem, Jinan 250353, Peoples R China 2.Changzhou Univ, Inst Petrochem Technol, Changzhou 213164, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Shi Lei,Xu Yan,Xing Li-shu,et al. Synthesis and characterization of ordered mesoporous carbons CMK-3 produced by tailoring the mesopores of an AlSBA-15hard template synthesized without acid[J]. NEW CARBON MATERIALS,2014,29(6):515-521.
APA	Shi Lei,Xu Yan,Xing Li-shu,Li Xiang-ping,Yang Cheng,&Lin Sen.(2014).Synthesis and characterization of ordered mesoporous carbons CMK-3 produced by tailoring the mesopores of an AlSBA-15hard template synthesized without acid.NEW CARBON MATERIALS,29(6),515-521.
MLA	Shi Lei,et al."Synthesis and characterization of ordered mesoporous carbons CMK-3 produced by tailoring the mesopores of an AlSBA-15hard template synthesized without acid".NEW CARBON MATERIALS 29.6(2014):515-521.