Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal-Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids

doi:10.1071/CH13633

QIBEBT-IR > 仿生与固态能源系统研究组

	Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal-Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids
	Xu, Jiakun 1,2; Sun, Xiaochun 3; Yan, Xingchen 2,4; Zhang, Dongmei 2; Sun, Mi 1
	2014
发表期刊	AUSTRALIAN JOURNAL OF CHEMISTRY
卷号	67 期号:6 页码:901-906
摘要	We successfully synthesized two new metal coordination polymers [Cd-3(bdc)(3)(L)(3)(H2O)(3)](n) (1) and [Co(tda)(L)](n) (2) (H(2)bdc = 1,2-benzenedicarboxylic acid, H(2)tda = 2,5-thiophendicarboxylic acid, and L = 3,5-bis(benzimidazol-1-yl) pyridine), which were then characterized by IR, and elemental, X-ray powder diffraction, and X-ray single-crystal diffraction analysis. Complex 1 possesses a uninodal three-connected hcb Shubnikov hexagonal plane net with {6(3)} topology. Complex 2 features a three-connected topological net with {8(2) . 10} topology (so-called 'tongue-and-groove' structure). A typical T-shaped molecular bilayer motif, which has rarely been reported previously, was successfully constructed by strategically selecting H(2)tda as the second ligand. In addition, the solid-state photoluminescent spectra of 1 and 2 were measured at room temperature.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1071/CH13633
关键词[WOS]	COORDINATION POLYMERS ; BIS(IMIDAZOLE) LIGANDS ; IMIDAZOLE ; COMPLEXES ; CD(II) ; ZN(II)
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000337727600010
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6166
专题	仿生与固态能源系统研究组
作者单位	1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Minist Agr, Key Lab Sustainable Dev Marine Fisheries, Qingdao 266071, Peoples R China 2.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China 3.Natl Oceanog Ctr, Qingdao 266071, Peoples R China 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,et al. Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal-Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2014,67(6):901-906.
APA	Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,Zhang, Dongmei,&Sun, Mi.(2014).Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal-Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids.AUSTRALIAN JOURNAL OF CHEMISTRY,67(6),901-906.
MLA	Xu, Jiakun,et al."Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal-Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids".AUSTRALIAN JOURNAL OF CHEMISTRY 67.6(2014):901-906.