| Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide | |
Xu, Xianrui1,2; Pan, Xiaobo1; Tang, Sifu1 ; Lv, Xiaoxia1,2; Li, Liangjun1,2; Wu, Jincai3; Zhao, Xuebo1
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| 2013-03-01 | |
| 发表期刊 | INORGANIC CHEMISTRY COMMUNICATIONS
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| 卷号 | 29期号:1页码:89-93 |
| 摘要 | Two sodium complexes, [(mu(3)-MDBP)Na-2(THF)(2)](2)[(mu(3)-OCH2CH2OCH3)Na](2) (1) and [(mu(1)-MDBP)Na(mu(2)-H2O)(THF)](2)(THF)(2) (2) have been synthesized and structurally characterized. Experimental results show that complex 1 initiates efficiently the ring opening polymerization of L-lactide in a controlled fashion, yielding polymers with narrow polydispersity indexes in a wide range of monomer-to-initiator ratios. (c) 2013 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Sodium Complexes Catalyst Ring Opening Polymerization Polydispersity Indexes |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.inoche.2012.12.029 |
| 关键词[WOS] | CYCLIC ESTERS ; EPSILON-CAPROLACTONE ; RAC-LACTIDE ; MAGNESIUM COMPLEXES ; KETIMINATE COMPLEXES ; ALUMINUM COMPLEXES ; SELECTIVE BINDING ; METAL-COMPLEXES ; ZINC-COMPLEXES ; INITIATORS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| WOS记录号 | WOS:000316532300022 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6027 |
| 专题 | 多相催化转化研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Beijing 100864, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Xianrui,Pan, Xiaobo,Tang, Sifu,et al. Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,29(1):89-93. |
| APA | Xu, Xianrui.,Pan, Xiaobo.,Tang, Sifu.,Lv, Xiaoxia.,Li, Liangjun.,...&Zhao, Xuebo.(2013).Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide.INORGANIC CHEMISTRY COMMUNICATIONS,29(1),89-93. |
| MLA | Xu, Xianrui,et al."Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of L-lactide".INORGANIC CHEMISTRY COMMUNICATIONS 29.1(2013):89-93. |
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