Fabrication, characterization and electrochemistry of organic-inorganic multilayer films containing polyoxometalate and polyviologen via layer-by-layer self-assembly

doi:10.1016/j.matchemphys.2013.05.047

QIBEBT-IR > 多相催化转化研究组

	Fabrication, characterization and electrochemistry of organic-inorganic multilayer films containing polyoxometalate and polyviologen via layer-by-layer self-assembly
	Zhang, Hong-Yu 1,2; Miao, Aimg Ji 1; Jiang, Min 3
	2013-08-15
发表期刊	MATERIALS CHEMISTRY AND PHYSICS
卷号	141 期号:1 页码:482-487
摘要	The novel organic-inorganic multilayer films containing poly(butanyl viologen) (abbreviated as PBV) and phosphomolybdic acid (H3PMo12O40, abbreviated as PMo12) have been fabricated on quartz slides, silicon wafers and glassy carbon electrode by the layer-by-layer self-assembly technique. The highly ordered multilayer films were characterized by the UV-visible spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray reflectometry (XRR), Atomic force microscopy (AFM) and cyclic voltammetry. UV-visible spectra revealed that the growth of the films for each deposition cycle was reproducible. FT-IR and XPS spectra confirmed the incorporation of PBV and PMo12 into the multilayer films. XRR revealed the film thickness at nanoscale, and AFM showed film surface with uniform and smooth morphology. In addition, the electrochemical behavior of the multilayer films at room temperature was investigated. As a result, the films presented good electrocatalytic activity toward BrO3-, H2O2 and NO2-, providing valuable information for exploring the potential applications in BrO3- sensors. (C) 2013 Elsevier B.V. All rights reserved.
文章类型	Article
关键词	Multilayers Thin Films Heterostructures Electrochemical Techniques
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.matchemphys.2013.05.047
关键词[WOS]	POST-BASE TREATMENT ; TRIS(2,2'-BIPYRIDINE) RUTHENIUM(II) ; BIFUNCTIONAL ELECTROCATALYST ; POLY(ACRYLIC ACID) ; COMPOSITE FILMS ; ELECTRODE ; SURFACE ; POLY(4-VINYLPYRIDINE) ; MONOLAYER ; ANION
收录类别	SCI
语种	英语
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000322149700067
引用统计	被引频次：25[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6022
专题	多相催化转化研究组
作者单位	1.Ocean Univ China, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Peoples R China 2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Energy Utilizat Technol Ctr, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Hong-Yu,Miao, Aimg Ji,Jiang, Min. Fabrication, characterization and electrochemistry of organic-inorganic multilayer films containing polyoxometalate and polyviologen via layer-by-layer self-assembly[J]. MATERIALS CHEMISTRY AND PHYSICS,2013,141(1):482-487.
APA	Zhang, Hong-Yu,Miao, Aimg Ji,&Jiang, Min.(2013).Fabrication, characterization and electrochemistry of organic-inorganic multilayer films containing polyoxometalate and polyviologen via layer-by-layer self-assembly.MATERIALS CHEMISTRY AND PHYSICS,141(1),482-487.
MLA	Zhang, Hong-Yu,et al."Fabrication, characterization and electrochemistry of organic-inorganic multilayer films containing polyoxometalate and polyviologen via layer-by-layer self-assembly".MATERIALS CHEMISTRY AND PHYSICS 141.1(2013):482-487.