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A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols
Lei Zhang; Mo Xian; Yucai He; Liangzhi Li; Jianming Yang; Shitao Yu; Xin Xu
2009
发表期刊Bioresource Technology
ISSNISSN: 0960-8524
卷号100期号:19页码:4368–4373
摘要Biodiesel could be synthesized using Bronsted acidic ionic liquid N-methyl-2-pyrrolidonium methyl sulfonate ([NMP][CH(3)SO(3)]) as a catalyst, specially with free long-chain fatty acids or their mixtures, as well as with low-molecular weight alcohols as substrates. This catalyst showed good catalytic and reusable performance under mild conditions and without any additional organic solvent. The ionic liquid could be reused eight times after the water in the ionic liquid was removed. The yields of fatty acid alkyl esters could reach between 93.6% and 95.3% after the esterifications were carried out at 70 degrees C for 8 h. Therefore, an efficient and environmentally friendly catalyst was provided for the synthesis of biodiesel from low-cost feedstocks such as waste oils.
关键词Ionic Liquid N-Methyl-2-pyrrolidonium Methyl Sulfonate Esterification Free Fatty Acid Biodiesel
学科领域生物基化学品
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/440
专题生物基材料组群
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GB/T 7714
Lei Zhang,Mo Xian,Yucai He,et al. A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols[J]. Bioresource Technology,2009,100(19):4368–4373.
APA Lei Zhang.,Mo Xian.,Yucai He.,Liangzhi Li.,Jianming Yang.,...&Xin Xu.(2009).A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols.Bioresource Technology,100(19),4368–4373.
MLA Lei Zhang,et al."A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols".Bioresource Technology 100.19(2009):4368–4373.
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