A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols | |
Lei Zhang; Mo Xian; Yucai He; Liangzhi Li; Jianming Yang; Shitao Yu; Xin Xu | |
2009 | |
发表期刊 | Bioresource Technology |
ISSN | ISSN: 0960-8524 |
卷号 | 100期号:19页码:4368–4373 |
摘要 | Biodiesel could be synthesized using Bronsted acidic ionic liquid N-methyl-2-pyrrolidonium methyl sulfonate ([NMP][CH(3)SO(3)]) as a catalyst, specially with free long-chain fatty acids or their mixtures, as well as with low-molecular weight alcohols as substrates. This catalyst showed good catalytic and reusable performance under mild conditions and without any additional organic solvent. The ionic liquid could be reused eight times after the water in the ionic liquid was removed. The yields of fatty acid alkyl esters could reach between 93.6% and 95.3% after the esterifications were carried out at 70 degrees C for 8 h. Therefore, an efficient and environmentally friendly catalyst was provided for the synthesis of biodiesel from low-cost feedstocks such as waste oils. |
关键词 | Ionic Liquid N-Methyl-2-pyrrolidonium Methyl Sulfonate Esterification Free Fatty Acid Biodiesel |
学科领域 | 生物基化学品 |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/440 |
专题 | 生物基材料组群 |
推荐引用方式 GB/T 7714 | Lei Zhang,Mo Xian,Yucai He,et al. A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols[J]. Bioresource Technology,2009,100(19):4368–4373. |
APA | Lei Zhang.,Mo Xian.,Yucai He.,Liangzhi Li.,Jianming Yang.,...&Xin Xu.(2009).A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols.Bioresource Technology,100(19),4368–4373. |
MLA | Lei Zhang,et al."A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols".Bioresource Technology 100.19(2009):4368–4373. |
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