| Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture | |
| Chen, Xianghui1,2; Qiao, Shanlin1; Du, Zhengkun1; Zhou, Yuanhang1; Yang, Renqiang1 | |
| 2013-07-25 | |
| 发表期刊 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 卷号 | 34期号:14页码:1181-1185 |
| 摘要 | A novel kind of functional organic microporous polymer is designed by introducing polar organic groups (P=O and P=S) and electron-rich heterocyclic into the framework to obtain high carbon dioxide capture capacity. The estimated Brunauer-Emmett-Teller (BET) surface areas of these polymers are about 600 m(2) g(-1) and the highest CO2 uptake is 2.26 mmol g(-1) (1.0 bar/273 K). Interestingly, the polymer containing P=O groups shows greater CO2 capture capacity than that containing P=S groups at the same temperature. In addition, these polymers show high isosteric heats of CO2 adsorption (28.6 kJ mol(-1)), which can be competitive with some nitrogen-rich networks. Therefore, these microporous polymers are promising candidates for carbon dioxide capture. |
| 文章类型 | Article |
| 关键词 | Functionalization Of Polymers Gas Capture Property Heat Capacity Thienyl-phosphine Networks |
| 学科领域 | 先进功能有机材料 |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/marc.201300328 |
| 关键词[WOS] | HIGH-SURFACE-AREA ; METAL-ORGANIC FRAMEWORK ; GAS-STORAGE ; CO2 ; SEPARATION ; NETWORKS ; SIMULATION ; COPOLYMER ; POROSITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| WOS记录号 | WOS:000325870200010 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1702 |
| 专题 | 先进有机功能材料研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Xianghui,Qiao, Shanlin,Du, Zhengkun,et al. Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2013,34(14):1181-1185. |
| APA | Chen, Xianghui,Qiao, Shanlin,Du, Zhengkun,Zhou, Yuanhang,&Yang, Renqiang.(2013).Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture.MACROMOLECULAR RAPID COMMUNICATIONS,34(14),1181-1185. |
| MLA | Chen, Xianghui,et al."Synthesis and Characterization of Functional Thienyl-Phosphine Microporous Polymers for Carbon Dioxide Capture".MACROMOLECULAR RAPID COMMUNICATIONS 34.14(2013):1181-1185. |
| 条目包含的文件 | 下载所有文件 | |||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Synthesis and Charac（1611KB） | 开放获取 | CC BY-NC-SA | 浏览 下载 | |||
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论