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Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water
Xicheng Wang; Feng Wu; Yijun Jiang; Jing Guan; Shengxi Yao; Xindong Mu
2012
发表期刊Chemistry Letters
卷号41期号:1页码:476-479
摘要
Ni-Cu/ZnO catalysts with varied Ni-to-Cu mole ratio were prepared by coprecipitation and evaluated for the hydrogenolysis of high-crystalline cellulose. Ni and Cu species exerted synergetic effects in dehydroxylation reaction and C-C bond breakage for the formation of 1,2-alkanediols. Ni-Cu/ZnO with Ni-to-Cu ratio of 2:3 is highly selective toward 1,2-alkanediols (72.5%) under hydrothermal conditions (518 K, 4 MPa H-2), which also exhibits excellent activity in the conversion of real biomass.
 
学科领域绿色化学催化
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/1397
专题绿色化学催化研究组
推荐引用方式
GB/T 7714
Xicheng Wang,Feng Wu,Yijun Jiang,et al. Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water[J]. Chemistry Letters,2012,41(1):476-479.
APA Xicheng Wang,Feng Wu,Yijun Jiang,Jing Guan,Shengxi Yao,&Xindong Mu.(2012).Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water.Chemistry Letters,41(1),476-479.
MLA Xicheng Wang,et al."Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water".Chemistry Letters 41.1(2012):476-479.
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文件名: NiCu ZnO-catalyzed Hydrogenolysis of Cellulose for the Production of 1 2-Alkanediols in Hot Compressed Water.pdf
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