Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water | |
Xicheng Wang; Feng Wu; Yijun Jiang; Jing Guan; Shengxi Yao; Xindong Mu | |
2012 | |
发表期刊 | Chemistry Letters |
卷号 | 41期号:1页码:476-479 |
摘要 |
Ni-Cu/ZnO catalysts with varied Ni-to-Cu mole ratio were prepared by coprecipitation and evaluated for the hydrogenolysis of high-crystalline cellulose. Ni and Cu species exerted synergetic effects in dehydroxylation reaction and C-C bond breakage for the formation of 1,2-alkanediols. Ni-Cu/ZnO with Ni-to-Cu ratio of 2:3 is highly selective toward 1,2-alkanediols (72.5%) under hydrothermal conditions (518 K, 4 MPa H-2), which also exhibits excellent activity in the conversion of real biomass.
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学科领域 | 绿色化学催化 |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1397 |
专题 | 绿色化学催化研究组 |
推荐引用方式 GB/T 7714 | Xicheng Wang,Feng Wu,Yijun Jiang,et al. Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water[J]. Chemistry Letters,2012,41(1):476-479. |
APA | Xicheng Wang,Feng Wu,Yijun Jiang,Jing Guan,Shengxi Yao,&Xindong Mu.(2012).Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water.Chemistry Letters,41(1),476-479. |
MLA | Xicheng Wang,et al."Ni-Cu/ZnO catalyzed hydrogenolysis of cellulose for the production of 1,2-alkanediols in hot-compressed water".Chemistry Letters 41.1(2012):476-479. |
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