| Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl | |
| Guo, Xingcui; Cao, Quan; Jiang, Yijun; Guan, Jing; Wang, Xiaoyan; Mu, Xindong | |
| 2012-04-01 | |
| 发表期刊 | CARBOHYDRATE RESEARCH
 |
| 卷号 | 351期号:3页码:35-41 |
| 摘要 | Mesoporous SBA-15 materials functionalized with propylsulfonic acid groups (SBA-15-SO(3)H) were synthesized through a conventional one-pot route. It was used as a catalyst for the selective synthesis of 5-hydroxymethylfurfural (HMF) from the dehydration of fructose using BmimCl as solvent. Reaction time, temperature and fructose concentration were investigated during the HMF synthesis procedure. The catalyst SBA-15-SO(3)H exhibits high fructose conversion (near 100%) and HMF selectivity (about 81%) with good stability in the HMF synthesis. It was a suitable catalyst to produce HMF from renewable carbohydrates in potential industrial process. ; Mesoporous SBA-15 materials functionalized with propylsulfonic acid groups (SBA-15-SO3H) were synthesized through a conventional one-pot route. It was used as a catalyst for the selective synthesis of 5-hydroxymethylfurfural (HMF) from dehydration of fructose using BmimCl as solvent. Reaction time, temperature and fructose concentration were investigated during the HMF synthesis procedure. The catalyst SBA-15-SO3H exhibits high fructose conversion (near 100%) and HMF selectivity (about 81%) with good stability in the HMF synthesis. It was a suitable catalyst to produce HMF from renewable carbohydrates in potential industrial process. (C) 2012 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 关键词 | 5-hydroxymethylfurfural (Hmf) Fructose Dehydration Acid Catalysts Ionic Liquids |
| 学科领域 | 绿色化学催化 |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| DOI | 10.1016/j.carres.2012.01.003 |
| 关键词[WOS] | SULFONIC-ACID GROUPS ; EXCHANGE-RESIN ; ONE-POT ; CONVERSION ; EFFICIENT ; BIOMASS ; SILICA ; CHEMICALS ; SUCROSE ; SOLVENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS类目 | Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic |
| WOS记录号 | WOS:000301128300004 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1396 |
| 专题 | 绿色化学催化研究组 |
| 作者单位 | Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xingcui,Cao, Quan,Jiang, Yijun,et al. Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl[J]. CARBOHYDRATE RESEARCH,2012,351(3):35-41. |
| APA | Guo, Xingcui,Cao, Quan,Jiang, Yijun,Guan, Jing,Wang, Xiaoyan,&Mu, Xindong.(2012).Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl.CARBOHYDRATE RESEARCH,351(3),35-41. |
| MLA | Guo, Xingcui,et al."Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid BmimCl".CARBOHYDRATE RESEARCH 351.3(2012):35-41. |
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