Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water

doi:10.3390/catal8050193

QIBEBT-IR

	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
	Li, Yaru 1,2; Guo, Xingcui2 ; Liu, Daosheng 1; Mu, Xindong 2; Chen, Xiufang2 ; Shi, Yan 1
	2018-05-01
发表期刊	CATALYSTS
ISSN	2073-4344
卷号	8 期号:5
摘要	Co-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the catalyst. The 10%Co-10%Ni/TiO2 catalyst showed the highest selectivity toward CPO (53.3%) with almost complete FFA conversion, and the main product was CPL (45.4%) over 20%Co/TiO2 at the optimized conditions (150 degrees C, 4 MPa H-2, 4 h). The surface morphology, surface area, composition and reducibility properties of these catalysts were fully characterized by XRD, H-2-TPR, ICP-AES and SEM. The factors that influenced the activity of catalysts were also investigated in detail. Additionally, the stability of catalyst for the hydrogenative rearrangement of FFA was studied.
文章类型	Article
关键词	Furfural Co-ni Catalyst Cyclopentanone Cyclopentanol Hydrogenation
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.3390/catal8050193
关键词[WOS]	BIMETALLIC CATALYSTS ; COBALT CATALYSTS ; SUPPORTED COBALT ; CARBON ; HYDROGENATION ; CHEMICALS ; TRANSFORMATION ; REARRANGEMENT ; NANOTUBES ; COMPOUND
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China(21433001 ; key basic research project of Shandong Natural Science Foundation(ZR201708240147) ; Young Taishan Scholars Program of Shandong Province(tsqn 20161052) ; 21406251)
WOS类目	Chemistry, Physical
WOS记录号	WOS:000435191500022
出版者	MDPI
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/11378
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Guo, Xingcui; Shi, Yan
作者单位	1.Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, 1 Dandong Rd, Fushun 113001, Liaoning, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Li, Yaru,Guo, Xingcui,Liu, Daosheng,et al. Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water[J]. CATALYSTS,2018,8(5).
APA	Li, Yaru,Guo, Xingcui,Liu, Daosheng,Mu, Xindong,Chen, Xiufang,&Shi, Yan.(2018).Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water.CATALYSTS,8(5).
MLA	Li, Yaru,et al."Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water".CATALYSTS 8.5(2018).