QIBEBT-IR  > 热化学转化研究组
Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor
Liu, Xinxin1,2; He, Tao1,4; Ge, Yuanzheng1,2; Li, Guomin3; Wu, Jingli1; Wang, Zhiqi1; Liu, Guangbo1; Wu, Jinhu1
2018-05-01
Source PublicationJOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
ISSN0165-2370
Volume131Pages:128-133
AbstractCatalytic upgrading of anisole and guaiacol in an atmospheric dielectric barrier discharge (DBD) plasma reactor was studied. Compared to thermal upgrading in a fixed bed, the DBD plasma method can convert the model compound to benzene and toluene with high selectivity under relatively low temperature. The synergistic effect between H-2 plasma and Ni-Mo/SiO2 catalyst is crucial to the high deoxygenation rate. The primary reactions occurring during the DBD upgrading process include demethylation, methyl transfer, and hydrogenolysis. XRD spectra indicate that phase change should not be the primary reason for catalyst deactivation; GC-MS, NH3-TPD, and regeneration experiments show that carbon deposition is the cause for deactivation. NH3-TPD analysis reveals that a combination of medium and strong acid sites plays an important role in the hydrogenolysis of phenols to benzenes. The present work shows DBD catalytic upgrading as a promising route for the C-O bond hydrogenolysis reaction.
SubtypeArticle
KeywordLignin Upgrading Dbd Plasma Anisole Guaiacol Catalytic Deaxygentadon
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jaap.2018.01.007
WOS KeywordBIO-OIL ; PHASE HYDRODEOXYGENATION ; REACTION NETWORK ; ANISOLE ; GUAIACOL ; CONVERSION ; BIOMASS ; 4-METHYLANISOLE ; HYDROGENATION ; HYDROCARBONS
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Spectroscopy
Funding OrganizationNational Natural Science Foundation of China(11375249) ; Foundation of Key Laboratory of Low-Carbon Conversion Science & Engineering, Shanghai Advanced Research Institute(KLLCCSE-201704) ; Sichuan Science and Technology Project(2017JZ0021) ; Natural Science Foundation of Shandong Province(ZR2016EEQ15)
WOS SubjectChemistry, Analytical ; Spectroscopy
WOS IDWOS:000429393000014
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qibebt.ac.cn/handle/337004/10758
Collection热化学转化研究组
Corresponding AuthorHe, Tao; Wu, Jinhu
Affiliation1.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Qingdao Univ, Sch Chem & Chem Engn, Qingdao 266071, Peoples R China
4.Chinese Acad Sci, Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xinxin,He, Tao,Ge, Yuanzheng,et al. Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2018,131:128-133.
APA Liu, Xinxin.,He, Tao.,Ge, Yuanzheng.,Li, Guomin.,Wu, Jingli.,...&Wu, Jinhu.(2018).Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,131,128-133.
MLA Liu, Xinxin,et al."Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 131(2018):128-133.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Xinxin]'s Articles
[He, Tao]'s Articles
[Ge, Yuanzheng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Xinxin]'s Articles
[He, Tao]'s Articles
[Ge, Yuanzheng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Xinxin]'s Articles
[He, Tao]'s Articles
[Ge, Yuanzheng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.