| Three-Component Functional Additive in a LiPF6-Based Carbonate Electrolyte for a High-Voltage LiCoO2/Graphite Battery System | |
| Pang, Chunguang1,2; Xu, Gaojie2; An, Weizhong1; Ding, Guoliang2; Liu, Xiaochen2; Chai, Jingchao2; Ma, Jun2; Liu, Haisheng2; Cui, Guanglei2 | |
| 2017-11-01 | |
| 发表期刊 | ENERGY TECHNOLOGY
 |
| 卷号 | 5期号:11页码:1979-1989 |
| 摘要 | The effectiveness of multicomponent functional additives on the performances of lithium ion batteries has received increasing attention. Tris(2H-hexafluoroisopropyl) borate (THFPB) additive can totally suppress the appearance of a crystallized complex between LiPF6 and adiponitrile (ADN). Herein, ADN, THFPB, and cyclohexylbenzene are demonstrated to be an effective three-component functional additive in LiPF6-based carbonate electrolyte that improves the cyclability and rate capabilities of LiCoO2/graphite full cells charged to 4.4, 4.45, and 4.5 V, respectively. By systematic characterization, it is demonstrated rationally that, with the help of the three-component functional additive, the electrolyte is stabilized and new types of less resistant, thinner, more protective solid-electrolyte interfaces are constructed simultaneously on the surfaces of both electrodes. |
| 文章类型 | Article |
| 关键词 | Additives Batteries Carbonate Electrolytes High Voltage Synergistic Effects |
| WOS标题词 | Science & Technology ; Technology |
| DOI | 10.1002/ente.201700118 |
| 关键词[WOS] | LITHIUM-ION BATTERIES ; LICOO2 CATHODE MATERIALS ; ATOMIC LAYER DEPOSITION ; ANION RECEPTORS ; ELECTROCHEMICAL PERFORMANCE ; COMPOSITE ELECTRODES ; RECENT PROGRESS ; POUCH CELLS ; 4.5 V ; LI |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Energy & Fuels |
| 项目资助者 | CAS-QIBEBT Director Innovation Foundation ; Qingdao Energy Storage Industry Scientific Research ; Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation of China(51502319 ; Shandong Provincial Natural Science Foundation(ZR2015QZ01 ; 21473228) ; BS2015CL006) |
| WOS类目 | Energy & Fuels |
| WOS记录号 | WOS:000417576700010 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9945 |
| 专题 | 仿生与固态能源系统研究组 |
| 作者单位 | 1.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pang, Chunguang,Xu, Gaojie,An, Weizhong,et al. Three-Component Functional Additive in a LiPF6-Based Carbonate Electrolyte for a High-Voltage LiCoO2/Graphite Battery System[J]. ENERGY TECHNOLOGY,2017,5(11):1979-1989. |
| APA | Pang, Chunguang.,Xu, Gaojie.,An, Weizhong.,Ding, Guoliang.,Liu, Xiaochen.,...&Cui, Guanglei.(2017).Three-Component Functional Additive in a LiPF6-Based Carbonate Electrolyte for a High-Voltage LiCoO2/Graphite Battery System.ENERGY TECHNOLOGY,5(11),1979-1989. |
| MLA | Pang, Chunguang,et al."Three-Component Functional Additive in a LiPF6-Based Carbonate Electrolyte for a High-Voltage LiCoO2/Graphite Battery System".ENERGY TECHNOLOGY 5.11(2017):1979-1989. |
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| Three-Component Func（4232KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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