| A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin | |
| Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan; Xiao Wang and Xiaobo Wan | |
| 2017-10-23 | |
| Source Publication | Org. Chem. Front
 |
| Issue | 1Pages:1 |
| Abstract | Brominated thiazoloisoindigo was synthesized for the first time from thiazoloisatin, which was obtained via an unprecedented nucleophilic cyclization strategy. Thiazoloisoindigo was shown to exhibit a deeper LUMO energy level than isoindigo and thienoisoindigo, which makes it a potential building block for n-type semiconductors. Moreover, brominated thiazoloisoindigo is sensitive toward nucleophilic attack, and its reaction with aniline resulted in an unexpectedly much more stable acceptor with a LUMO energy level as low as −3.82 eV |
| Subtype | Article |
| DOI | 10.1039/c7QO00841D |
| Indexed By | SCI |
| WOS ID | WOS:000424012100017 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qibebt.ac.cn/handle/337004/9927 |
| Collection | 生物基及仿生高分子材料团队（过去） |
| Corresponding Author | Xiao Wang and Xiaobo Wan |
| Affiliation | CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy & Bioprocess Technology, Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,Xiao Wang and Xiaobo Wan. A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin[J]. Org. Chem. Front,2017(1):1. |
| APA | Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,&Xiao Wang and Xiaobo Wan.(2017).A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin.Org. Chem. Front(1),1. |
| MLA | Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,et al."A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin".Org. Chem. Front .1(2017):1. |
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