A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin

doi:10.1039/c7QO00841D

	A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin
	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan; Xiao Wang and Xiaobo Wan
	2017-10-23
发表期刊	Org. Chem. Front
期号	1 页码:1
摘要	Brominated thiazoloisoindigo was synthesized for the first time from thiazoloisatin, which was obtained via an unprecedented nucleophilic cyclization strategy. Thiazoloisoindigo was shown to exhibit a deeper LUMO energy level than isoindigo and thienoisoindigo, which makes it a potential building block for n-type semiconductors. Moreover, brominated thiazoloisoindigo is sensitive toward nucleophilic attack, and its reaction with aniline resulted in an unexpectedly much more stable acceptor with a LUMO energy level as low as −3.82 eV
文章类型	Article
DOI	10.1039/c7QO00841D
收录类别	SCI
WOS记录号	WOS:000424012100017
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9927
专题	生物基及仿生高分子材料团队（过去）
通讯作者	Xiao Wang and Xiaobo Wan
作者单位	CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy & Bioprocess Technology, Chinese Academy of Sciences
推荐引用方式 GB/T 7714	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,Xiao Wang and Xiaobo Wan. A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin[J]. Org. Chem. Front,2017(1):1.
APA	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,&Xiao Wang and Xiaobo Wan.(2017).A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin.Org. Chem. Front(1),1.
MLA	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,et al."A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin".Org. Chem. Front .1(2017):1.