Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots

doi:10.1002/cssc.201701127

QIBEBT-IR > 低碳催化转化研究组

	Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots
	Ji, Guijie 1; Duan, Yanan 1; Zhang, Shaochun 1; Fei, Benhua 2; Chen, Xiufang 1; Yang, Yong 1
	2017-09-11
发表期刊	CHEMSUSCHEM
卷号	10 期号:17 页码:3427-3434
摘要	Highly dispersed palladium nanoparticles (Pd NPs) immobilized on heteroatom-doped hierarchical porous carbon supports (N,O-carbon) with large specific surface areas are synthesized by a wet chemical reduction method. The N,O-carbon derived from naturally abundant bamboo shoots is fabricated by a tandem hydrothermal-carbonization process without assistance of any templates, chemical activation reagents, or exogenous N or O sources in a simple and ecofriendly manner. The prepared Pd/N,O-carbon catalyst shows extremely high activity and excellent chemoselectivity for semihydrogenation of a broad range of alkynes to versatile and valuable alkenes under ambient conditions. The catalyst can be readily recovered for successive reuse with negligible loss in activity and selectivity, and is also applicable for practical gram-scale reactions.
文章类型	Article
关键词	Alkyne Hydrogenation Carbon Materials Nanoparticles Semihydrogenation Palladium
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/cssc.201701127
关键词[WOS]	NANOPOROUS GOLD CATALYST ; STEREOSELECTIVE SEMIHYDROGENATION ; CIS-ALKENES ; HYDROGENATION REACTIONS ; PALLADIUM ; EFFICIENT ; REDUCTION ; DESIGN ; WATER ; SUPERCAPACITORS
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences(Y6710619KL) ; 13th Five-Year National key R D projects(2017YFD0600805)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000410136800016
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9739
专题	低碳催化转化研究组
作者单位	1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Int Ctr Bamboo & Rattan, Beijing 100102, Peoples R China
推荐引用方式 GB/T 7714	Ji, Guijie,Duan, Yanan,Zhang, Shaochun,et al. Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots[J]. CHEMSUSCHEM,2017,10(17):3427-3434.
APA	Ji, Guijie,Duan, Yanan,Zhang, Shaochun,Fei, Benhua,Chen, Xiufang,&Yang, Yong.(2017).Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots.CHEMSUSCHEM,10(17),3427-3434.
MLA	Ji, Guijie,et al."Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots".CHEMSUSCHEM 10.17(2017):3427-3434.