Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot

doi:10.1039/c7ra08569a

QIBEBT-IR > 生物基材料组群

	Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot
	Zhang, Song 1,2; Xu, Chao1,2 ; Zhai, Guoqing 1; Zhao, Mingliang 1; Xian, Mo1 ; Jia, Yuxiang 1; Yu, Zongjiang 1; Liu, Fusheng 2; Jian, Fangfang 2; Sun, Weizhi1
	2017
发表期刊	RSC ADVANCES
卷号	7 期号:75 页码:47539-47546
摘要	A new type of bimetallic palladium and aluminum incorporated mobile crystalline materials (Pd-Al-MCM-41) as bifunctional catalysts has been hydrothermally synthesized. Characterization shows that these molecular materials exhibit an ordered mesoporous structure, high surface area and a good dispersion of palladium in the frame. The catalytic activity of the Pd-Al-MCM-41 for the dimerization-hydrogenation reaction system of beta-pinene in one pot has been systematically studied. Pd-0.5-Al-30-MCM-41 (SiO2/Al2O3 = 30, 0.5 wt% palladium content) was found to be the best catalyst which gave a dimer yield of up to 64.7%. It is worth noting that palladium shows a good synergic catalytic effect with aluminum in the dimerization reaction and enhances the dimerization yield. Furthermore, the bifunctional catalyst displayed a good activity over 4 runs.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c7ra08569a
关键词[WOS]	MCM-41 ; ISOMERIZATION ; POLYMERIZATION ; ZEOLITES ; ACIDITY ; FUELS
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of Shandong Province(ZR2016BQ39)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000412977000037
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9731
专题	生物基材料组群
作者单位	1.Chinese Acad Sci, Qingdao Inst Biomass Energy & Bioproc Technol, Inst Biotechnol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Song,Xu, Chao,Zhai, Guoqing,et al. Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot[J]. RSC ADVANCES,2017,7(75):47539-47546.
APA	Zhang, Song.,Xu, Chao.,Zhai, Guoqing.,Zhao, Mingliang.,Xian, Mo.,...&Sun, Weizhi.(2017).Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot.RSC ADVANCES,7(75),47539-47546.
MLA	Zhang, Song,et al."Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot".RSC ADVANCES 7.75(2017):47539-47546.