QIBEBT-IR  > 多相催化转化团队
Nickel Phosphides Supported on HZSM-5 for Catalytic Hydrodeoxygenation of Eugenol: Effect of Phosphorus Content
Qi, Jingbo1,2; Tang, Si-Fu1; Sun, Yuanyuan1; Xu, Chen1,2; Li, Xuebing1
2017-08-31
发表期刊CHEMISTRYSELECT
卷号2期号:25页码:7525-7529
摘要Nickel phosphides supported on HZSM-5 zeolite with different initial P/Ni molar ratios were prepared for catalytic hydrodeoxygenation (HDO) of eugenol to produce hydrocarbons. When P/Ni<0.5, the increase of P content gave smaller and more uniform particles which was helpful for hydrogenation of aromatic ring, while the total acid sites of the catalyst decreased due to the coverage of more acid sites of HZSM-5 by adding P which was unfavourable for the removal of oxygen. At P/Ni=0.5, the active phase supported on HZSM-5 was mainly Ni3P with the smallest average particle size and minimum amount of acid sites which could account for the best hydrogenation activity and the lowest selectivity of hydrocarbons, respectively. Further increasing the P/Ni ratio up to 1 and 2, the active phase became Ni2P and a lot of nonuniform Ni2P nanorod crystals appeared on and out of the support HZSM-5 which caused a sharp drop in the hydrogenation activity of the catalyst. For a combination of hydrogenation and deoxygenation considerations, The P/Ni=0.25 is the best ratio for nickel phosphides supported on HZSM-5 zeolite to HDO of lignin-related phenols.
文章类型Article
关键词Hydrodeoxygenation Lignin Nickel Phosphide Supported Catalysts Zeolites
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/slct.201701391
关键词[WOS]NI2P/SIO2 ; GUAIACOL ; OIL ; DEHYDROGENATION ; HYDROGENATION ; REMOVAL ; BIOMASS ; SITES ; ACID ; NI
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者National Natural Science Foundation of China(21276263 ; U1162203 ; 21676287)
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000409870000007
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9722
专题多相催化转化团队
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Qi, Jingbo,Tang, Si-Fu,Sun, Yuanyuan,et al. Nickel Phosphides Supported on HZSM-5 for Catalytic Hydrodeoxygenation of Eugenol: Effect of Phosphorus Content[J]. CHEMISTRYSELECT,2017,2(25):7525-7529.
APA Qi, Jingbo,Tang, Si-Fu,Sun, Yuanyuan,Xu, Chen,&Li, Xuebing.(2017).Nickel Phosphides Supported on HZSM-5 for Catalytic Hydrodeoxygenation of Eugenol: Effect of Phosphorus Content.CHEMISTRYSELECT,2(25),7525-7529.
MLA Qi, Jingbo,et al."Nickel Phosphides Supported on HZSM-5 for Catalytic Hydrodeoxygenation of Eugenol: Effect of Phosphorus Content".CHEMISTRYSELECT 2.25(2017):7525-7529.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Qi, Jingbo]的文章
[Tang, Si-Fu]的文章
[Sun, Yuanyuan]的文章
百度学术
百度学术中相似的文章
[Qi, Jingbo]的文章
[Tang, Si-Fu]的文章
[Sun, Yuanyuan]的文章
必应学术
必应学术中相似的文章
[Qi, Jingbo]的文章
[Tang, Si-Fu]的文章
[Sun, Yuanyuan]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。