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Li4Ti5O12-based energy conversion and storage systems: Status and prospects
Xu, Gaojie1; Han, Pengxian1; Dong, Shanmu1; Liu, Haisheng1; Cui, Guanglei1; Chen, Liquan1,2
2017-07-15
发表期刊COORDINATION CHEMISTRY REVIEWS
卷号343页码:139-184
摘要The "zero-strain" spinel lithium titanate oxide (Li4Ti5O12) has been extensively studied as one of the most promising alternatives to carbon materials in energy conversion and storage devices, because of its negligible volume change (only 0.2-0.3%), ultrahigh rate capability, excellent safety characteristics (suppressed formation of solid-electrolyte interphase (SEI) layer and avoided growth of lithium dendrites) and cycling stability (intrinsic zero strain). However, the commercial large-scale applications of LTO-based Li-ion batteries (LIBs) and Li-ion capacitors (LICs) are greatly limited presently. This review mainly concentrates on full cells of LTO-based LIBs and LICs from basic research to applied research. As for various types of LTO-based LIBs, issues on material-cell performance relationships, compatibility of electrolytes, specific applications, overall cost analysis, safety evaluations, gassing mechanisms/remedies, and flexible/micro cell designs, are elaborated. This review also makes a concise summary of the evolution of electrochemical capacitors (ECs), and an exhaustive description of various types of LTO-based LICs on issues of new electrode materials, electrolyte optimization, and cell balancing. Finally, some helpful perspectives are provided to promote the future development of LTO-based LIBs and LICs with high performances. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Review
关键词Lithium Titanate Oxide Li-ion Batteries Li-ion Capacitors
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.ccr.2017.05.006
关键词[WOS]LITHIUM-ION BATTERIES ; HIGH-VOLTAGE SPINEL ; HYBRID-ELECTRIC-VEHICLE ; REDOX SHUTTLE ADDITIVES ; HIGH-RATE CAPABILITY ; LEAD-FREE BATTERIES ; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ; ACCELERATING RATE CALORIMETRY ; SOLID-ELECTROLYTE-INTERPHASE ; SULFONE-BASED ELECTROLYTES
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者"135" Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation of China(51502319 ; Shandong Provincial Natural Science Foundation(ZR201613Q18) ; Youth Innovation Promotion Association CAS(2017253) ; 21473228)
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000406168500003
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9720
专题仿生与固态能源系统研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China
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Xu, Gaojie,Han, Pengxian,Dong, Shanmu,et al. Li4Ti5O12-based energy conversion and storage systems: Status and prospects[J]. COORDINATION CHEMISTRY REVIEWS,2017,343:139-184.
APA Xu, Gaojie,Han, Pengxian,Dong, Shanmu,Liu, Haisheng,Cui, Guanglei,&Chen, Liquan.(2017).Li4Ti5O12-based energy conversion and storage systems: Status and prospects.COORDINATION CHEMISTRY REVIEWS,343,139-184.
MLA Xu, Gaojie,et al."Li4Ti5O12-based energy conversion and storage systems: Status and prospects".COORDINATION CHEMISTRY REVIEWS 343(2017):139-184.
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