Li4Ti5O12-based energy conversion and storage systems: Status and prospects | |
Xu, Gaojie1; Han, Pengxian1; Dong, Shanmu1; Liu, Haisheng1; Cui, Guanglei1; Chen, Liquan1,2 | |
2017-07-15 | |
发表期刊 | COORDINATION CHEMISTRY REVIEWS |
卷号 | 343页码:139-184 |
摘要 | The "zero-strain" spinel lithium titanate oxide (Li4Ti5O12) has been extensively studied as one of the most promising alternatives to carbon materials in energy conversion and storage devices, because of its negligible volume change (only 0.2-0.3%), ultrahigh rate capability, excellent safety characteristics (suppressed formation of solid-electrolyte interphase (SEI) layer and avoided growth of lithium dendrites) and cycling stability (intrinsic zero strain). However, the commercial large-scale applications of LTO-based Li-ion batteries (LIBs) and Li-ion capacitors (LICs) are greatly limited presently. This review mainly concentrates on full cells of LTO-based LIBs and LICs from basic research to applied research. As for various types of LTO-based LIBs, issues on material-cell performance relationships, compatibility of electrolytes, specific applications, overall cost analysis, safety evaluations, gassing mechanisms/remedies, and flexible/micro cell designs, are elaborated. This review also makes a concise summary of the evolution of electrochemical capacitors (ECs), and an exhaustive description of various types of LTO-based LICs on issues of new electrode materials, electrolyte optimization, and cell balancing. Finally, some helpful perspectives are provided to promote the future development of LTO-based LIBs and LICs with high performances. (C) 2017 Elsevier B.V. All rights reserved. |
文章类型 | Review |
关键词 | Lithium Titanate Oxide Li-ion Batteries Li-ion Capacitors |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.ccr.2017.05.006 |
关键词[WOS] | LITHIUM-ION BATTERIES ; HIGH-VOLTAGE SPINEL ; HYBRID-ELECTRIC-VEHICLE ; REDOX SHUTTLE ADDITIVES ; HIGH-RATE CAPABILITY ; LEAD-FREE BATTERIES ; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ; ACCELERATING RATE CALORIMETRY ; SOLID-ELECTROLYTE-INTERPHASE ; SULFONE-BASED ELECTROLYTES |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
项目资助者 | "135" Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation of China(51502319 ; Shandong Provincial Natural Science Foundation(ZR201613Q18) ; Youth Innovation Promotion Association CAS(2017253) ; 21473228) |
WOS类目 | Chemistry, Inorganic & Nuclear |
WOS记录号 | WOS:000406168500003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9720 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Gaojie,Han, Pengxian,Dong, Shanmu,et al. Li4Ti5O12-based energy conversion and storage systems: Status and prospects[J]. COORDINATION CHEMISTRY REVIEWS,2017,343:139-184. |
APA | Xu, Gaojie,Han, Pengxian,Dong, Shanmu,Liu, Haisheng,Cui, Guanglei,&Chen, Liquan.(2017).Li4Ti5O12-based energy conversion and storage systems: Status and prospects.COORDINATION CHEMISTRY REVIEWS,343,139-184. |
MLA | Xu, Gaojie,et al."Li4Ti5O12-based energy conversion and storage systems: Status and prospects".COORDINATION CHEMISTRY REVIEWS 343(2017):139-184. |
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