Novel Design Concepts of Efficient Mg-Ion Electrolytes toward High-Performance Magnesium-Selenium and Magnesium-Sulfur Batteries | |
Zhang, Zhonghua1,2; Cui, Zili1; Qiao, Lixin3; Guan, Jing3; Xu, Huimin3; Wang, Xiaogang1; Hu, Pu1; Du, Huiping1; Li, Shizhen3; Zhou, Xinhong3; Dong, Shanmu1; Liu, Zhihong1; Cui, Guanglei1; Chen, Liquan4 | |
2017-06-07 | |
发表期刊 | ADVANCED ENERGY MATERIALS |
卷号 | 7期号:11 |
摘要 | Developing high-voltage Mg-compatible electrolytes (>3.0V vs Mg) still remains to be the biggest R&D challenge in the area of nonaqueous rechargeable Mg batteries. Here, the key design concepts toward exploring new boron-based Mg salts in a specific way of highlighting the implications of anions are proposed for the first time. The well-defined boron-centered anion-based magnesium electrolyte (BCM electrolyte) is successfully presented by facile one-step mixing of tris(2H-hexafluoroisopropyl) borate and MgF2 in 1,2-dimethoxyethane, in which the structures of anions have been thoroughly investigated via mass spectrometry accompanied by NMR and Raman spectra. The first all-round practical BCM electrolyte fulfills all requirements of easy synthesis, high ionic conductivity, wide potential window (3.5 V vs Mg), compatibility with electrophilic sulfur, and simultaneously noncorrosivity to coin cell assemblies. When utilizing the BCM electrolyte, the fast-kinetics selenium/carbon (Se/C) cathode achieves the best rate capability and the sulfur/carbon (S/C) cathode exhibits an impressive prolonged cycle life than previously published reports. The BCM electrolyte offers the most promising avenue to eliminate the major roadblocks on the way to high-voltage Mg batteries and the design concepts can shed light on future exploration directions toward high-voltage Mg-compatible electrolytes. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1002/aenm.201602055 |
关键词[WOS] | STABLE LITHIUM-SALTS ; STABILITY ; CATHODE ; ADDITIVES ; CHEMISTRY ; SYSTEMS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
项目资助者 | National High Technology Research and Development Program of China (863 Program)(2014AA052303) ; National Natural Science Foundation of China program(21271180) ; Key Technology Research Projects of Qingdao(13-CX-10) |
WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
WOS记录号 | WOS:000402967200018 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9658 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100190, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 102488, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zhonghua,Cui, Zili,Qiao, Lixin,et al. Novel Design Concepts of Efficient Mg-Ion Electrolytes toward High-Performance Magnesium-Selenium and Magnesium-Sulfur Batteries[J]. ADVANCED ENERGY MATERIALS,2017,7(11). |
APA | Zhang, Zhonghua.,Cui, Zili.,Qiao, Lixin.,Guan, Jing.,Xu, Huimin.,...&Chen, Liquan.(2017).Novel Design Concepts of Efficient Mg-Ion Electrolytes toward High-Performance Magnesium-Selenium and Magnesium-Sulfur Batteries.ADVANCED ENERGY MATERIALS,7(11). |
MLA | Zhang, Zhonghua,et al."Novel Design Concepts of Efficient Mg-Ion Electrolytes toward High-Performance Magnesium-Selenium and Magnesium-Sulfur Batteries".ADVANCED ENERGY MATERIALS 7.11(2017). |
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