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High Performance Lithium Secondary Batteries Based on Novel Ni3Co6S8@C Core-Shell Nanoparticle
Yan, Xingchen1; Fu, Lin1; Wang, Xiaogang1; Xiao, Dongdong2; Ma, Jun1; Zhang, Jianjun1; Gu, Lin2; Cui, Guanglei1
2017-08-01
发表期刊JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷号17期号:8页码:5384-5390
摘要As one new type of cathode materials, transition metal sulfides with the advantages of high energy density and high electronic conductivity have attracted a lot of attentions to fulfill the demands of high power and energy battery applications in hybrid electric vehicles (HEVs) and electric vehicles (EVs). Herein, we report the synthesis of one novel ternary sulfide of Ni3Co6S8@C urchin-like core-shell nanoparticles as cathode materials for lithium secondary batteries with sodium alginate as the binder and lithium foil as the anode. The novel Ni3Co6S8@C nanoparticles show high discharge specific capacity, excellent cycling stability and much better rate capability. Based on the overall mass of the Ni3Co6S8@C nanoparticles, it could achieve an initial energy density of 957 Wh kg(-1), and a respective energy density of 606 and 508 Wh kg(-1) after 100 and 200 cycles. The outstanding performance of the Ni3Co6S8@C electrode could be attributed to the carbon coating and sodium alginate binder, because these strategies could significantly inhibit the volume change, aggregation and pulverization of Ni3Co6S8@C nanoparticles.
文章类型Article
关键词Ternary Sulfide Ni3co6s8@c Core-shell Nanoparticle Cathode Material Lithium Secondary Battery
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1166/jnn.2017.13795
关键词[WOS]LI-ION BATTERY ; SULFUR BATTERIES ; ANODE MATERIAL ; ELECTROCHEMICAL PERFORMANCE ; STORAGE PROPERTIES ; CATHODE MATERIALS ; HOLLOW SPHERES ; GRAPHENE OXIDE ; THIN-FILMS ; CARBON
收录类别SCI
语种英语
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
项目资助者National Natural Science Foundation of China(21271180 ; Shandong Provincial Natural Science Foundation(BS2015CL006) ; 21473228 ; 51502319)
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000404914400031
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9635
专题仿生与固态能源系统研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Solar Energy Utilizat & Energy St, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
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Yan, Xingchen,Fu, Lin,Wang, Xiaogang,et al. High Performance Lithium Secondary Batteries Based on Novel Ni3Co6S8@C Core-Shell Nanoparticle[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2017,17(8):5384-5390.
APA Yan, Xingchen.,Fu, Lin.,Wang, Xiaogang.,Xiao, Dongdong.,Ma, Jun.,...&Cui, Guanglei.(2017).High Performance Lithium Secondary Batteries Based on Novel Ni3Co6S8@C Core-Shell Nanoparticle.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,17(8),5384-5390.
MLA Yan, Xingchen,et al."High Performance Lithium Secondary Batteries Based on Novel Ni3Co6S8@C Core-Shell Nanoparticle".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 17.8(2017):5384-5390.
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