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Enteromorpha prolifera-derived carbon as a high-performance cathode material for lithium-sulfur batteries
Wang, Yanqing1,2; Zhang, Zengqi1; Zhu, Shaoyin1; Sun, Deye1; Jin, Yongcheng1
2017-05-01
发表期刊JOURNAL OF APPLIED ELECTROCHEMISTRY
卷号47期号:5页码:631-639
摘要A novel carbon material for use in lithium-sulfur batteries is fabricated from the seaweed Enteromorpha prolifera, a renewable source that grows rapidly in the sea near Qingdao, China, during the summer. The E. prolifera-derived carbon (EPC) possesses a multilevel micropore-mesopore structure and a certain amount of oxygen- and nitrogen-containing functional groups. In addition, the hierarchical porous carbon also possesses a high specific surface area of 3536.58 m(2) g(-1) and a large pore volume of 1.754 cm(3) g(-1). The carbon can thus be loaded with a high sulfur content (EPC/S, 74.8 wt%), making it a promising candidate for use as the cathode material in lithium-sulfur batteries. The EPC was characterized using field-emission scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, the Brunauer-Emmett-Teller method, and other methods. The EPC/S cathode exhibited superior electrochemical performance; the first discharge capacity was as high as 1328 mA h g(-1) at 0.1 C. Further, the capacity was 520 mA h g(-1) after 100 cycles at 0.5 C and 510 mA h g(-1) after 100 cycles at 1 C.
文章类型Article
关键词Enteromorpha Prolifera Lithium-sulfur Battery Carbon Cathode Material Multilevel Micropore-mesopore Structure
WOS标题词Science & Technology ; Physical Sciences
DOI10.1007/s10800-017-1068-z
关键词[WOS]POROUS CARBON ; SUSTAINABLE SOURCE ; ENERGY-STORAGE ; SUPERCAPACITORS ; ELECTRODES ; GRAPHENE
收录类别SCI
语种英语
WOS研究方向Electrochemistry
项目资助者"100 Talents" program of Chinese Academy of Sciences ; CAS Key Laboratory of Bio-based Materials of Qingdao Institute of Bioenergy and Bioprocess Technology
WOS类目Electrochemistry
WOS记录号WOS:000399894700007
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9619
专题先进界面技术研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquanlu Rd, Beijing 100049, Peoples R China
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Wang, Yanqing,Zhang, Zengqi,Zhu, Shaoyin,et al. Enteromorpha prolifera-derived carbon as a high-performance cathode material for lithium-sulfur batteries[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY,2017,47(5):631-639.
APA Wang, Yanqing,Zhang, Zengqi,Zhu, Shaoyin,Sun, Deye,&Jin, Yongcheng.(2017).Enteromorpha prolifera-derived carbon as a high-performance cathode material for lithium-sulfur batteries.JOURNAL OF APPLIED ELECTROCHEMISTRY,47(5),631-639.
MLA Wang, Yanqing,et al."Enteromorpha prolifera-derived carbon as a high-performance cathode material for lithium-sulfur batteries".JOURNAL OF APPLIED ELECTROCHEMISTRY 47.5(2017):631-639.
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