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Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin
Chen, Tianju; Li, Lingyue; Zhao, Ruidong; Wu, Jinhu
2017-06-01
发表期刊JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷号128期号:3页码:1825-1832
摘要The pyrolysis kinetic analysis of the three pseudocomponents of biomass, namely cellulose, hemicellulose and lignin, were investigated using a thermogravimetric (TG) analyzer. The multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The activation energies of three pseudocomponents pyrolysis were evaluated using sinusoidally modulated temperature method. The results showed that the multi-peaks methods can fit the DTG curves of cellulose, hemicellulose and lignin successfully. There was only one reaction stage for the pyrolysis of cellulose and hemicelluloses. There were two reaction stages for the pyrolysis of lignin. The average E was 112.6, 162.8 and 156.8 kJ mol(-1) for cellulose, hemicellulose and lignin, respectively.
文章类型Article
关键词Pyrolysis Biomass Kinetic Analysis Pseudocomponent Sinusoidally Modulated Temperature Method
WOS标题词Science & Technology ; Physical Sciences
DOI10.1007/s10973-016-6040-3
关键词[WOS]BIO-OIL ; ACTIVATION-ENERGIES ; MODULATED THERMOGRAVIMETRY ; LIGNOCELLULOSIC BIOMASS ; STRAW PYROLYSIS ; REACTION MODEL ; DECOMPOSITION ; TEMPERATURE ; BIOCHAR ; REACTOR
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry
项目资助者National Natural Science Foundation of China(51406220) ; Shanxi Province Coal-based Key Technology Research and Development Program(MD 2014-03)
WOS类目Thermodynamics ; Chemistry, Analytical ; Chemistry, Physical
WOS记录号WOS:000401349800054
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9609
专题热化学转化研究组
作者单位Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc, Key Lab Biofuels, 189 Songling Rd, Qingdao 266101, Peoples R China
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Chen, Tianju,Li, Lingyue,Zhao, Ruidong,et al. Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2017,128(3):1825-1832.
APA Chen, Tianju,Li, Lingyue,Zhao, Ruidong,&Wu, Jinhu.(2017).Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,128(3),1825-1832.
MLA Chen, Tianju,et al."Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 128.3(2017):1825-1832.
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