Synthesis and Properties of 2D Carbon-Graphdiyne

doi:10.1021/acs.accounts.7b00205

QIBEBT-IR > 碳基材料与能源应用研究组

	Synthesis and Properties of 2D Carbon-Graphdiyne
	Jia, Zhiyu 1; Li, Yongjun 1,2; Zuo, Zicheng 1; Liu, Huibiao 1,2; Huang, Changshui 3; Li, Yuliang 1,2
	2017-10-01
发表期刊	ACCOUNTS OF CHEMICAL RESEARCH
卷号	50 期号:10 页码:2470-2478
摘要	CONSPECTUS: Graphdiyne (GDY) is a flat material comprising sp(2)- and sp-hybridized carbon atoms with high degrees of pi conjugation that features uniformly distributed pores. It is interesting not only from a structural point of view but also from the perspective of its electronic, chemical, mechanical, and magnetic properties. We have developed an in situ homocoupling reaction of hexaethynylbenzene on Cu foil for the fabrication of large-area ordered films of graphdiyne. These films are uniform and composed of graphdiyne multilayers. The conductivity of graphdiyne films, calculated at 2.52 x 10(-4) S m(-1), is comparable to that of Si, suggesting excellent semiconducting properties. Through morphology-controlled syntheses, we have prepared several well-defined graphdiyne structures (e.g., nanotubes, nanowires, and nanowalls) having distinct properties. The graphdiyne nanotube arrays and graphdiyne nanowalls exhibited excellent field emission performance, higher than that of some other semiconductors such as graphite and carbon nanotubes. These structures have several promising applications, for example, as energy storage materials and as anode materials in batteries. The unique atomic arrangement and electronic structure of graphdiyne also inspired us to use it to develop highly efficient catalysts; indeed, its low reduction potential and highly conjugated electronic structure allow graphdiyne to be used as a reducing agent and stabilizer for the electroless deposition of highly dispersed and surfactant-free Pd clusters. GDY-based three-dimensional (3D) nanoarchitectures featuring well-defined porous network structures can function as highly active cathodes for H-2 evolution. Heteroatom-doped GDY structures are excellent metal-free electrocatalysts for the oxygen reduction reaction (ORR). Its excellent electrocatalytic activity and inexpensive, convenient, and scalable preparation make GDY a promising candidate for practical and efficient energy applications; indeed, we have explored the application of GDY as a highly efficient lithium storage material and have elucidated the method through which lithium storage occurs in multilayer GDY. Lithium-ion batteries featuring GDY-based electrodes display excellent electrochemical performance, including high specific capacity, outstanding rate performance, and long cycle life. We have also explored the application of GDY in energy conversion and found that it exhibits excellent conductivity.
文章类型	Review
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1021/acs.accounts.7b00205
关键词[WOS]	NITROGEN-DOPED GRAPHDIYNE ; ALL-CARBON ; HYDROGEN-PRODUCTION ; LITHIUM STORAGE ; ION STORAGE ; SOLAR-CELLS ; GRAPHENE ; ELECTROCATALYST ; PREDICTIONS ; MOBILITY
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China(21790050 ; National Key Research and Development Project of China(2016YFA0200104) ; Key Program of the Chinese Academy of Sciences(QYZDY-SSW-SLH015) ; 21790051)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000413392000007
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9598
专题	碳基材料与能源应用研究组
作者单位	1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Organ Solids, Inst Chem,BNLMS, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Jia, Zhiyu,Li, Yongjun,Zuo, Zicheng,et al. Synthesis and Properties of 2D Carbon-Graphdiyne[J]. ACCOUNTS OF CHEMICAL RESEARCH,2017,50(10):2470-2478.
APA	Jia, Zhiyu,Li, Yongjun,Zuo, Zicheng,Liu, Huibiao,Huang, Changshui,&Li, Yuliang.(2017).Synthesis and Properties of 2D Carbon-Graphdiyne.ACCOUNTS OF CHEMICAL RESEARCH,50(10),2470-2478.
MLA	Jia, Zhiyu,et al."Synthesis and Properties of 2D Carbon-Graphdiyne".ACCOUNTS OF CHEMICAL RESEARCH 50.10(2017):2470-2478.