Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic

doi:10.1016/j.elecom.2017.09.001

QIBEBT-IR > 仿生与固态能源系统研究组

	Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic
	Xu, Huimin 1,2; Zhang, Zhonghua 1; Cui, Zili1 ; Du, Aobing 1; Lu, Chenglong 2; Dong, Shanmu 1; Ma, Jun1 ; Zhou, Xinhong 2; Cui, Guanglei1
	2017-10-01
发表期刊	ELECTROCHEMISTRY COMMUNICATIONS
卷号	83 页码:72-76
摘要	Herein we present a strong anion receptor-assisted Mg-ion electrolyte, which is synthesized from tris(2H-hexafluoroisopropyl) borate (THFPB) and MgO in 1,2-dimethoxyethane (DME). The as-prepared borate magnesium oxide complex (BMOC) electrolyte delivers exceptional electrochemical performances, including extremely high anodic stability (up to 4.2 V vs. Mg), non-corrosivity to stainless steel and aluminium foils, and reasonable ionic conductivity of 1.74 x 10(-4) S cm(-1). In addition, by virtue of the non-nucleophilic characteristic of the BMOC electrolyte, S\|\| BMOC\|\| Mg cells have been assembled, which show a high stable discharge capacity of 1030 mAh g(-1) for 15 cycles and one well-defined voltage plateau of approximate to 1.1 V vs. Mg, yielding a desirable energy density beyond 1100 Wh kg(-1) based on the weight of sulfur in cathodes.
文章类型	Article
关键词	Strong Anion Receptor Mg-ion Electrolyte High Anodic Stability Sulfur Cathode High Energy Density
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1016/j.elecom.2017.09.001
关键词[WOS]	RECHARGEABLE MAGNESIUM BATTERIES ; CATHODE ; PERFORMANCE ; SALTS ; DEPOSITION ; CHLORIDE ; SYSTEMS ; SULFUR
收录类别	SCI
语种	英语
WOS研究方向	Electrochemistry
项目资助者	National Science Fund for Distinguished Young Scholars(51625204) ; Youth Innovation Promotion Association of CAS(2016193) ; National Natural Science Foundation of China(51502319)
WOS类目	Electrochemistry
WOS记录号	WOS:000411349500016
引用统计	被引频次：53[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9592
专题	仿生与固态能源系统研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Xu, Huimin,Zhang, Zhonghua,Cui, Zili,et al. Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic[J]. ELECTROCHEMISTRY COMMUNICATIONS,2017,83:72-76.
APA	Xu, Huimin.,Zhang, Zhonghua.,Cui, Zili.,Du, Aobing.,Lu, Chenglong.,...&Cui, Guanglei.(2017).Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic.ELECTROCHEMISTRY COMMUNICATIONS,83,72-76.
MLA	Xu, Huimin,et al."Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic".ELECTROCHEMISTRY COMMUNICATIONS 83(2017):72-76.