| Understanding Mn-Based Intercalation Cathodes from Thermodynamics and Kinetics | |
| Xie, Yin1; Jin, Yongcheng2; Xiang, Lan1 | |
| 2017-07-01 | |
| 发表期刊 | CRYSTALS
 |
| 卷号 | 7期号:7 |
| 摘要 | A series of Mn-based intercalation compounds have been applied as the cathode materials of Li-ion batteries, such as LiMn2O4, LiNi1-x-yCoxMnyO2, etc. With open structures, intercalation compounds exhibit a wide variety of thermodynamic and kinetic properties depending on their crystal structures, host chemistries, etc. Understanding these materials from thermodynamic and kinetic points of view can facilitate the exploration of cathodes with better electrochemical performances. This article reviews the current available thermodynamic and kinetic knowledge on Mn-based intercalation compounds, including the thermal stability, structural intrinsic features, involved redox couples, phase transformations as well as the electrical and ionic conductivity. |
| 文章类型 | Review |
| 关键词 | Lithium Battery Mn-based Cathodes Thermodynamics Kinetics |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.3390/cryst7070221 |
| 关键词[WOS] | LITHIUM-ION BATTERIES ; HIGH-VOLTAGE SPINEL ; PULSED-LASER DEPOSITION ; TRANSITION-METAL OXIDE ; X-RAY-DIFFRACTION ; ELECTROCHEMICAL PROPERTIES ; LINI0.5MN1.5O4 CATHODE ; MANGANESE OXIDES ; STRUCTURAL STABILITY ; ELECTRONIC-STRUCTURE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Crystallography ; Materials Science |
| 项目资助者 | National Science Foundation of China(51234003 ; 51374138) |
| WOS类目 | Crystallography ; Materials Science, Multidisciplinary |
| WOS记录号 | WOS:000407446200039 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9551 |
| 专题 | 先进界面技术研究组 |
| 作者单位 | 1.Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Yin,Jin, Yongcheng,Xiang, Lan. Understanding Mn-Based Intercalation Cathodes from Thermodynamics and Kinetics[J]. CRYSTALS,2017,7(7). |
| APA | Xie, Yin,Jin, Yongcheng,&Xiang, Lan.(2017).Understanding Mn-Based Intercalation Cathodes from Thermodynamics and Kinetics.CRYSTALS,7(7). |
| MLA | Xie, Yin,et al."Understanding Mn-Based Intercalation Cathodes from Thermodynamics and Kinetics".CRYSTALS 7.7(2017). |
| 条目包含的文件 | 条目无相关文件。 | |||||
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