Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups

doi:10.1080/00958972.2016.1267728

QIBEBT-IR > 先进界面技术研究组

	Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups
	Xu, Weixia 1; Zhang, Zengqi 2,3; Zhao, Xin 2; Li, Jun 2
	2017
发表期刊	JOURNAL OF COORDINATION CHEMISTRY
卷号	70 期号:4 页码:746-755
摘要	One metal-free porphyrin, modified by electron-withdrawing groups, was synthesized by introduction of two peripheral pyridyl substituents and two metal coordination polymers, {[Zn(C42H16F10N6)]2C(2)H(7)N}(n) (1) and {[Co(C42H16F10N6)]C2H7N}(n) (2), were synthesized solvothermally. In 1, each porphyrin connected four other porphyrin molecules to construct a 2-D network through coordination bonds. Similarly, in 2 every Co(II) porphyrin coordinated with four adjacent molecules to form a 2-D framework. Thermogravimetric analyses indicate that both 1 and 2 show high-thermal stabilities. The fluorescence data of 1 and 2 show that 1 may be a candidate for potential inorganic-organic photoactive materials. Catalytic oxidation results show that 2 displays high activity with the only product acetophenone quantitatively in 81.4%, and after six cycles, the catalytic activity slightly decreases. These features of 2, including the exceptional stability, and high catalytic activity, make it outstanding among MOFs reported in the literature.
文章类型	Article
关键词	Porphyrin Crystal Structure Alkylbenzene Oxidation Catalytic Activity
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1080/00958972.2016.1267728
关键词[WOS]	METALLOPORPHYRINIC FRAMEWORKS ; COORDINATION POLYMERS ; HIGHLY EFFICIENT ; SURFACE-AREA ; CATALYSIS ; OXIDATION ; DESIGN ; COMPLEXES ; LIGAND ; IONS
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	National Nature Science Foundation of China(21271148)
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000395054700012
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9337
专题	先进界面技术研究组
作者单位	1.Xianyang Nomal Univ, Coll Chem & Chem Engn, Xianyang, Peoples R China 2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian, Peoples R China 3.Chinese Acad Sci, Qingdao Inst BioEnergy & Bioproc Technol, Qingdao, Peoples R China
推荐引用方式 GB/T 7714	Xu, Weixia,Zhang, Zengqi,Zhao, Xin,et al. Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups[J]. JOURNAL OF COORDINATION CHEMISTRY,2017,70(4):746-755.
APA	Xu, Weixia,Zhang, Zengqi,Zhao, Xin,&Li, Jun.(2017).Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups.JOURNAL OF COORDINATION CHEMISTRY,70(4),746-755.
MLA	Xu, Weixia,et al."Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups".JOURNAL OF COORDINATION CHEMISTRY 70.4(2017):746-755.