Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate | |
Xin, Hongchuan1; Yang, Shilei2; An, Baigang2; An, Zengjian1 | |
2017 | |
发表期刊 | RSC ADVANCES |
卷号 | 7期号:22页码:13467-13472 |
摘要 | An efficient method for the selective oxychlorination of phenol to 2,4-dichlorophenol catalyzed by manganous(II) sulfate is developed using hydrogen chloride as a chlorinating source, hydrogen peroxide as an oxidant and water as a solvent. The catalyst has high activity and selectivity under mild conditions. The products are automatically isolated from aqueous solution, which also contains the catalyst at the end of the reaction, and hence product separation and catalyst recycling are both simple in this system. The performance of manganous(II) sulfate with the oxidative chlorinating system HCl/H2O2 indicates that this is a promising synthetic method for the manufacture of various 2,4-dichlorophenol derivatives. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1039/c7ra00319f |
关键词[WOS] | AROMATIC-COMPOUNDS ; CHLORINATION ; HALOGENATION ; BROMINATION ; CHLORIDE ; ACID ; ZEOLITES ; ARENES ; H2O2 ; TBHP |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
项目资助者 | Innovative Research Team in College and Universities of Liaoning Province(LT2014007) |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000395935300055 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9329 |
专题 | 生物基及仿生高分子材料团队(过去) |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Sci & Technol Liaoning, Sch Chem Engn, Anshan 114051, Peoples R China |
推荐引用方式 GB/T 7714 | Xin, Hongchuan,Yang, Shilei,An, Baigang,et al. Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate[J]. RSC ADVANCES,2017,7(22):13467-13472. |
APA | Xin, Hongchuan,Yang, Shilei,An, Baigang,&An, Zengjian.(2017).Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate.RSC ADVANCES,7(22),13467-13472. |
MLA | Xin, Hongchuan,et al."Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate".RSC ADVANCES 7.22(2017):13467-13472. |
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