Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate
Xin, Hongchuan1; Yang, Shilei2; An, Baigang2; An, Zengjian1
2017
发表期刊RSC ADVANCES
卷号7期号:22页码:13467-13472
摘要An efficient method for the selective oxychlorination of phenol to 2,4-dichlorophenol catalyzed by manganous(II) sulfate is developed using hydrogen chloride as a chlorinating source, hydrogen peroxide as an oxidant and water as a solvent. The catalyst has high activity and selectivity under mild conditions. The products are automatically isolated from aqueous solution, which also contains the catalyst at the end of the reaction, and hence product separation and catalyst recycling are both simple in this system. The performance of manganous(II) sulfate with the oxidative chlorinating system HCl/H2O2 indicates that this is a promising synthetic method for the manufacture of various 2,4-dichlorophenol derivatives.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c7ra00319f
关键词[WOS]AROMATIC-COMPOUNDS ; CHLORINATION ; HALOGENATION ; BROMINATION ; CHLORIDE ; ACID ; ZEOLITES ; ARENES ; H2O2 ; TBHP
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者Innovative Research Team in College and Universities of Liaoning Province(LT2014007)
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000395935300055
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9329
专题生物基及仿生高分子材料团队(过去)
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Univ Sci & Technol Liaoning, Sch Chem Engn, Anshan 114051, Peoples R China
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Xin, Hongchuan,Yang, Shilei,An, Baigang,et al. Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate[J]. RSC ADVANCES,2017,7(22):13467-13472.
APA Xin, Hongchuan,Yang, Shilei,An, Baigang,&An, Zengjian.(2017).Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate.RSC ADVANCES,7(22),13467-13472.
MLA Xin, Hongchuan,et al."Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate".RSC ADVANCES 7.22(2017):13467-13472.
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