Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst

doi:10.1002/slct.201601606

	Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst
	Hu, M. S. Liangning 1; Yu, Jianqiang 1; Xin, Hongchuan 2; An, Zengjian2 ; Sun, Wenshou 3
	2017
发表期刊	CHEMISTRYSELECT
卷号	2 期号:3 页码:949-952
摘要	A catalytic method for aerobic water-based oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone catalysed by copper(II) nitrate was achieved under mild conditions using dioxygen as an oxidant and water as a solvent. The catalyst shows high activity and selectivity in the direct oxidation of 2,3,6-trimethylphenol into trimethyl-1,4-benzoquinone. Since components used in the present system are cheap and available, our method offers a safe system in the synthesis of trimethyl-1,4-benzoquinone under halogen ions-free conditions.
文章类型	Article
关键词	Aerobic Oxidation C-h Activation Halogen Ions-free 2 3 Trimethyl-1 6-trimethylphenol 4-benzoquinone
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/slct.201601606
关键词[WOS]	HYDROGEN-PEROXIDE ; IONIC LIQUIDS ; BENZOQUINONES ; PHENOLS
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000395533100015
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9326
专题	生物基及仿生高分子材料团队（过去）
作者单位	1.Qingdao Univ, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 3.Qingdao Univ, Coll Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,et al. Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst[J]. CHEMISTRYSELECT,2017,2(3):949-952.
APA	Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,An, Zengjian,&Sun, Wenshou.(2017).Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst.CHEMISTRYSELECT,2(3),949-952.
MLA	Hu, M. S. Liangning,et al."Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst".CHEMISTRYSELECT 2.3(2017):949-952.