Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst
Hu, M. S. Liangning1; Yu, Jianqiang1; Xin, Hongchuan2; An, Zengjian2; Sun, Wenshou3
2017
发表期刊CHEMISTRYSELECT
卷号2期号:3页码:949-952
摘要A catalytic method for aerobic water-based oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone catalysed by copper(II) nitrate was achieved under mild conditions using dioxygen as an oxidant and water as a solvent. The catalyst shows high activity and selectivity in the direct oxidation of 2,3,6-trimethylphenol into trimethyl-1,4-benzoquinone. Since components used in the present system are cheap and available, our method offers a safe system in the synthesis of trimethyl-1,4-benzoquinone under halogen ions-free conditions.
文章类型Article
关键词Aerobic Oxidation C-h Activation Halogen Ions-free 2 3 Trimethyl-1 6-trimethylphenol 4-benzoquinone
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/slct.201601606
关键词[WOS]HYDROGEN-PEROXIDE ; IONIC LIQUIDS ; BENZOQUINONES ; PHENOLS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000395533100015
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9326
专题生物基及仿生高分子材料团队(过去)
作者单位1.Qingdao Univ, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China
3.Qingdao Univ, Coll Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
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GB/T 7714
Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,et al. Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst[J]. CHEMISTRYSELECT,2017,2(3):949-952.
APA Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,An, Zengjian,&Sun, Wenshou.(2017).Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst.CHEMISTRYSELECT,2(3),949-952.
MLA Hu, M. S. Liangning,et al."Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst".CHEMISTRYSELECT 2.3(2017):949-952.
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