H-pi Conjugated Molecule-Based Self-Assembly of Surfactants for Promoting Methane Hydrate Formation

doi:10.1021/acssuschemeng.6b01909

QIBEBT-IR > 工业生物燃气研究组

	H-pi Conjugated Molecule-Based Self-Assembly of Surfactants for Promoting Methane Hydrate Formation
	Wang, Fei; Guo, Gang; Luo, Sheng-Jun; Guo, Rong-Bo
	2017-02-01
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷号	5 期号:2 页码:1408-1415
摘要	Self-assembled structures of the cationic surfactant cetyltrimethylammonium bromide (CTAB) and reactive red-195 dye molecule (RR195) were achieved under the electrostatic interaction between CTAB and RR195 molecules, pi-pi interaction between RR195 molecules, and hydrophobic force between CTAB molecules. The self-assembled structure was named as CTAB@RR195 and used for the first time to promote methane hydrate formation. CTAB@RR195 appeared as cubic structures at 50-100 nm with -SO3-/-SO4- groups on the surface and therefore could provide a large area of solid/liquid interface during methane hydrate formation. As a result, CTAB@RR195 could not only reduce the methane hydrate growth periods from over 40 h when CTAB was used to 2-3 h but could also improve the methane uptake from 0.054 to 0.072 to about 0.108 mol gas/mol water.
文章类型	Article
关键词	Methane Hydrates Surfactants Sq-assembly Pi-pi Conjugate Promotion Effect
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1021/acssuschemeng.6b01909
关键词[WOS]	UNSTIRRED GAS/LIQUID SYSTEM ; SODIUM DODECYL-SULFATE ; NATURAL-GAS ; FORMATION KINETICS ; ACTIVATED CARBON ; FROZEN HYDRATE ; GROWTH ; DISSOCIATION ; NANOSPHERES ; MICELLES
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Engineering
项目资助者	National Natural Science Foundation of China(41276143) ; National Science and Technology Pillar Program(20140015) ; Key Research & Development Project of Shandong(2015GSF115037) ; Applied Basic Research Foundation of Qingdao City(14-2-4-21-jch)
WOS类目	Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号	WOS:000393634600021
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9314
专题	工业生物燃气研究组
作者单位	Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Shandong Ind Engn Lab Biogas Prod & Utilizat, Key Lab Biofuels, Qingdao 266101, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Wang, Fei,Guo, Gang,Luo, Sheng-Jun,et al. H-pi Conjugated Molecule-Based Self-Assembly of Surfactants for Promoting Methane Hydrate Formation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(2):1408-1415.
APA	Wang, Fei,Guo, Gang,Luo, Sheng-Jun,&Guo, Rong-Bo.(2017).H-pi Conjugated Molecule-Based Self-Assembly of Surfactants for Promoting Methane Hydrate Formation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(2),1408-1415.
MLA	Wang, Fei,et al."H-pi Conjugated Molecule-Based Self-Assembly of Surfactants for Promoting Methane Hydrate Formation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.2(2017):1408-1415.