Sustainable and Superior Heat-Resistant Alginate Nonwoven Separator of LiNi0.5Mn1.5O4/Li Batteries Operated at 55 degrees C

doi:10.1021/acsami.6b14352

QIBEBT-IR > 仿生与固态能源系统研究组

	Sustainable and Superior Heat-Resistant Alginate Nonwoven Separator of LiNi0.5Mn1.5O4/Li Batteries Operated at 55 degrees C
	Wen, Huijie 1,2; Zhang, Jianjun 2; Chai, Jingchao 2; Ma, Jun 2; Yue, Liping 2; Dong, Tiantian 2; Zang, Xiao 2; Liu, Zhihong 2; Zhang, Botao 1; Cui, Guanglei 2
	2017-02-01
发表期刊	ACS APPLIED MATERIALS & INTERFACES
卷号	9 期号:4 页码:3694-3701
摘要	High-voltage lithium-ion batteries have become a major research focus. As a major part of lithium batteries, the separator plays a critical role in the development of high-voltage lithium batteries. Herein, we demonstrated a sustainable and superior heat-resistant alginate nonwoven separator for high-voltage (5 V) lithium batteries. It was demonstrated that the resultant alginate nonwoven separator exhibited better mechanical property (37 MPa), superior thermal stability (up to 150 degrees C), and higher ionic conductivity (1.4 X 10(-3) S/cm) as compared to commercially available polyolefin (PP) separator. More impressively, the S V class LiNi0.5Mn15O4 (LNMO)/Li cell with this alginate nonwoven separator delivered much better cycling stability (maintaining 79.6% of its initial discharge capacity) than that (69.3%) of PP separator after 200 cycles at an elevated temperature of 55 degrees C. In addition, the LiFePO4/Li cell assembled with such alginate nonwoven separator could still charge and discharge normally even at an elevated temperature of 150 degrees C. The above-mentioned fascinating characteristics of alginate separator provide great probability for its application for high-voltage (5 V) lithium batteries at elevated temperatures.
文章类型	Article
关键词	Alginate Nonwoven Separator Sustainable Heat Resistant High Voltage Lithium Batteries
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acsami.6b14352
关键词[WOS]	LITHIUM-ION BATTERIES ; HIGH-VOLTAGE SPINEL ; ELECTROCHEMICAL PERFORMANCE ; COMPOSITE SEPARATOR ; POLYMER ELECTROLYTE ; MECHANICAL-PROPERTIES ; MEMBRANE ; TEMPERATURE ; BINDER ; CONDUCTIVITY
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science
项目资助者	Programs of the National Natural Science Foundation of China(21271180) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; Qingdao Institute of Bioenergy and Bioprocess Technology Director Innovation Foundation for Young Scientists(QIBEBT-DIFYS-201508) ; Shandong Provincial Natural Science Foundation, China(ZR2013FZ001)
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000393355900051
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9312
专题	仿生与固态能源系统研究组
作者单位	1.Qingdao Univ, Sch Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Wen, Huijie,Zhang, Jianjun,Chai, Jingchao,et al. Sustainable and Superior Heat-Resistant Alginate Nonwoven Separator of LiNi0.5Mn1.5O4/Li Batteries Operated at 55 degrees C[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(4):3694-3701.
APA	Wen, Huijie.,Zhang, Jianjun.,Chai, Jingchao.,Ma, Jun.,Yue, Liping.,...&Cui, Guanglei.(2017).Sustainable and Superior Heat-Resistant Alginate Nonwoven Separator of LiNi0.5Mn1.5O4/Li Batteries Operated at 55 degrees C.ACS APPLIED MATERIALS & INTERFACES,9(4),3694-3701.
MLA	Wen, Huijie,et al."Sustainable and Superior Heat-Resistant Alginate Nonwoven Separator of LiNi0.5Mn1.5O4/Li Batteries Operated at 55 degrees C".ACS APPLIED MATERIALS & INTERFACES 9.4(2017):3694-3701.