Novel Fe-W-Ce Mixed Oxide for the Selective Catalytic Reduction of NOx with NH3 at Low Temperatures | |
Stahl, Anna1,2; Wang, Zhong1; Schwaemmle, Tobias2; Ke, Jun3; Li, Xuebing1 | |
2017-02-01 | |
发表期刊 | CATALYSTS |
卷号 | 7期号:2 |
摘要 | A set of novel iron doped cerium-tungsten catalysts were prepared by sol-gel method with a view to their application for low temperature selective catalytic reduction (SCR) of NOx with NH3 in power plants. With a molar ratio Fe/W/Ce of 0.5:1:1, a NOx reduction of >90% at 200 degrees C was achieved. In Fe-W-Ce catalysts with low iron oxide content, it was found that the iron compounds were highly dispersed and formed a solid solution within the cerium oxide lattice, which promoted the SCR activity. Large amounts of iron in the catalysts might form a layer of Fe2O3 on the catalyst surface, which induced the synergistic inhibition effect among Fe, Ce and W species. Moreover, the Fe-W-Ce catalysts possessed a high resistance to changed operation parameters as well as to deactivation by SO2 and/or H2O. The novel catalyst showed to be competitive among recently developed low-temperature SCR catalysts. |
文章类型 | Article |
关键词 | Fe-w-ce Scr Synergistic Effect High Resistance Competitive |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.3390/catal7020071 |
关键词[WOS] | SCR CATALYST ; CEO2-WO3 CATALYSTS ; CERIA ; IRON ; OXIDATION ; AMMONIA ; CO ; PERFORMANCE ; ADSORPTION ; RESISTANCE |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
项目资助者 | National Natural Science Foundation of China(21607162 ; Doctoral Fund of Shandong Province(BS2015HZ003) ; Qingdao Indigenous Innovation Program(16-5-1-27-jch) ; Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering, MOE(KLIEEE-15-05) ; 21276263 ; 21506239) |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000395436800036 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9307 |
专题 | 多相催化转化研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.Univ Stuttgart, Inst Combust & Power Plant Technol, D-70569 Stuttgart, Germany 3.Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China |
推荐引用方式 GB/T 7714 | Stahl, Anna,Wang, Zhong,Schwaemmle, Tobias,et al. Novel Fe-W-Ce Mixed Oxide for the Selective Catalytic Reduction of NOx with NH3 at Low Temperatures[J]. CATALYSTS,2017,7(2). |
APA | Stahl, Anna,Wang, Zhong,Schwaemmle, Tobias,Ke, Jun,&Li, Xuebing.(2017).Novel Fe-W-Ce Mixed Oxide for the Selective Catalytic Reduction of NOx with NH3 at Low Temperatures.CATALYSTS,7(2). |
MLA | Stahl, Anna,et al."Novel Fe-W-Ce Mixed Oxide for the Selective Catalytic Reduction of NOx with NH3 at Low Temperatures".CATALYSTS 7.2(2017). |
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