| The search of proper oxygen carriers for chemical looping partial oxidation of carbon | |
Zhang, Jinzhi1; He, Tao1 ; Wang, Zhiqi1; Zhu, Min1,2; Zhang, Ke3; Li, Bin3; Wu, Jinhu1
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| 2017-03-15 | |
| 发表期刊 | APPLIED ENERGY
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| 卷号 | 190页码:1119-1125 |
| 摘要 | Chemical looping partial oxidation process has more advantages over conventional chemical looping process, which can not only completely avoid the problem of greenhouse gas emissions, but also supply syngas products for chemical industry. The aim of the present work is to perform fundamental investigation on chemical looping partial oxidation of solid fuels. Production of CO through chemical looping partial oxidation of carbon was investigated in order to find proper oxygen carrier with good reactivity and high selectivity. A simple and easy to use method based on the zone division of Ellingham diagram was offered to distinguish the oxidation ability of various metal oxides, and three zones including complete oxidation, partial oxidation and inert zones were divided. CaFe2O4, Ca2Fe2O5 and FeAl2O4 in partial oxidation zone together with Fe2O3 in complete oxidation zone were chosen as target oxygen carriers (OCs) for chemical looping partial oxidation of carbon in this work. Of the target metal oxides, CaFe2O4 and Ca2Fe2O5 were found to have fast reaction rate, large oxygen-carrying capacity, high CO selectivity, and good regeneration performance, which made them very attractive for the purpose of chemical looping partial oxidation of solid fuels in real applications. (C) 2017 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Chemical Looping Partial Oxidation Oxygen Carrier |
| WOS标题词 | Science & Technology ; Technology |
| DOI | 10.1016/j.apenergy.2017.01.024 |
| 关键词[WOS] | IRON-ORE ; SYNTHESIS GAS ; COMBUSTION ; GASIFICATION ; COAL ; METHANE ; TECHNOLOGY ; PYROLYSIS ; REACTOR ; OXIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 项目资助者 | Bilateral Inter-Governmental S&T Cooperation Proposal(2016YFE0108400) ; Entrepreneurial and Innovative Leading Talent Project of Qingdao(13-CX-19) ; Strategic Priority Research Program "Climate Change: Carbon Budget and Relevant Issues" of the Chinese Academy of Sciences(XDA07050102) ; National Natural Science Foundation of China(11375249) |
| WOS类目 | Energy & Fuels ; Engineering, Chemical |
| WOS记录号 | WOS:000395959100091 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9304 |
| 专题 | 热化学转化研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.CNTC, Zhengzhou Tobacco Res Inst, Zhengzhou 450001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jinzhi,He, Tao,Wang, Zhiqi,et al. The search of proper oxygen carriers for chemical looping partial oxidation of carbon[J]. APPLIED ENERGY,2017,190:1119-1125. |
| APA | Zhang, Jinzhi.,He, Tao.,Wang, Zhiqi.,Zhu, Min.,Zhang, Ke.,...&Wu, Jinhu.(2017).The search of proper oxygen carriers for chemical looping partial oxidation of carbon.APPLIED ENERGY,190,1119-1125. |
| MLA | Zhang, Jinzhi,et al."The search of proper oxygen carriers for chemical looping partial oxidation of carbon".APPLIED ENERGY 190(2017):1119-1125. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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