In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries

doi:10.1002/advs.201600377

QIBEBT-IR > 仿生与固态能源系统研究组

	In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries
	Chai, Jingchao 1,2; Liu, Zhihong 1; Ma, Jun1 ; Wang, Jia 1,2; Liu, Xiaochen 3; Liu, Haisheng1 ; Zhang, Jianjun1,2 ; Cui, Guanglei1 ; Chen, Liquan 4
	2017-02-01
发表期刊	ADVANCED SCIENCE
卷号	4 期号:2
摘要	Nowadays it is extremely urgent to seek high performance solid polymer electrolyte that possesses both interfacial stability toward lithium/graphitic anodes and high voltage cathodes for high energy density solid state batteries. Inspired by the positive interfacial effect of vinylene carbonate additive on solid electrolyte interface, a novel poly (vinylene carbonate) based solid polymer electrolyte is presented via a facile in situ polymerization process in this paper. It is manifested that poly (vinylene carbonate) based solid polymer electrolyte possess a superior electrochemical stability window up to 4.5 V versus Li/Li+ and considerable ionic conductivity of 9.82 x 10(-5) S cm(-1) at 50 degrees C. Moreover, it is demonstrated that high voltage LiCoO2/Libatteries using this solid polymer electrolyte display stable charge/discharge profiles, considerable rate capability, excellent cycling performance, and decent safety characteristic. It is believed that poly (vinylene carbonate) based electrolyte can be a very promising solid polymer electrolyte candidate for high energy density lithium batteries.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1002/advs.201600377
关键词[WOS]	IONIC-CONDUCTIVITY ; ELECTROCHEMICAL PROPERTIES ; RECHARGEABLE BATTERIES ; TRANSFERENCE NUMBERS ; COMPOSITE ; SUCCINONITRILE ; CONDUCTORS ; SEPARATOR ; COMPLEXES ; MEMBRANES
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
项目资助者	Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; Shandong Provincial Natural Science Foundation, China(ZR2015QZ01) ; "135" Projects Fund of CAS- QIBEBT Director Innovation Foundation
WOS类目	Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000397020800016
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9302
专题	仿生与固态能源系统研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Technol Inst, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Chai, Jingchao,Liu, Zhihong,Ma, Jun,et al. In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries[J]. ADVANCED SCIENCE,2017,4(2).
APA	Chai, Jingchao.,Liu, Zhihong.,Ma, Jun.,Wang, Jia.,Liu, Xiaochen.,...&Chen, Liquan.(2017).In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries.ADVANCED SCIENCE,4(2).
MLA	Chai, Jingchao,et al."In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries".ADVANCED SCIENCE 4.2(2017).