A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions
Xin, Hongchuan1; Hu, Liangning2; Yu, Jianqiang2; Sun, Wenshou3; An, Zengjian1
2017-04-01
发表期刊CATALYSIS COMMUNICATIONS
卷号93页码:1-4
摘要A highly efficient catalytic method for aerobic oxyiodination of various phenols catalysed by copper(11) nitrate was achieved under mild conditions using 12 as an iodinating reagent, molecular oxygen as an oxidant, and water as a solvent. The catalyst shows not only high activity for phenols with either electron-donating or electron-withdrawing groups, but also a remarkable selectivity for the formation of para-iodo substituted phenols. This study offers a green method for iodination of aromatic phenols with high atom economy. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Article
关键词Aerobic Oxyiodination Lodophenols Organic Solvent-free Green Catalytic Method
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.catcom.2017.01.019
关键词[WOS]OXIDATIVE IODINATION ; SODIUM-NITRITE ; AROMATIC-COMPOUNDS ; EFFICIENT ; ARENES ; BROMINATION ; PEROXIDE ; REAGENTS ; ALKYNES ; IODINE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000397685600001
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/9299
专题生物基及仿生高分子材料团队(过去)
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Qingdao Univ, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
3.Qingdao Univ, Coll Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
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GB/T 7714
Xin, Hongchuan,Hu, Liangning,Yu, Jianqiang,et al. A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions[J]. CATALYSIS COMMUNICATIONS,2017,93:1-4.
APA Xin, Hongchuan,Hu, Liangning,Yu, Jianqiang,Sun, Wenshou,&An, Zengjian.(2017).A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions.CATALYSIS COMMUNICATIONS,93,1-4.
MLA Xin, Hongchuan,et al."A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions".CATALYSIS COMMUNICATIONS 93(2017):1-4.
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