A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions | |
Xin, Hongchuan1; Hu, Liangning2; Yu, Jianqiang2; Sun, Wenshou3; An, Zengjian1 | |
2017-04-01 | |
发表期刊 | CATALYSIS COMMUNICATIONS |
卷号 | 93页码:1-4 |
摘要 | A highly efficient catalytic method for aerobic oxyiodination of various phenols catalysed by copper(11) nitrate was achieved under mild conditions using 12 as an iodinating reagent, molecular oxygen as an oxidant, and water as a solvent. The catalyst shows not only high activity for phenols with either electron-donating or electron-withdrawing groups, but also a remarkable selectivity for the formation of para-iodo substituted phenols. This study offers a green method for iodination of aromatic phenols with high atom economy. (C) 2017 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Aerobic Oxyiodination Lodophenols Organic Solvent-free Green Catalytic Method |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.catcom.2017.01.019 |
关键词[WOS] | OXIDATIVE IODINATION ; SODIUM-NITRITE ; AROMATIC-COMPOUNDS ; EFFICIENT ; ARENES ; BROMINATION ; PEROXIDE ; REAGENTS ; ALKYNES ; IODINE |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000397685600001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9299 |
专题 | 生物基及仿生高分子材料团队(过去) |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Qingdao Univ, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 3.Qingdao Univ, Coll Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Xin, Hongchuan,Hu, Liangning,Yu, Jianqiang,et al. A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions[J]. CATALYSIS COMMUNICATIONS,2017,93:1-4. |
APA | Xin, Hongchuan,Hu, Liangning,Yu, Jianqiang,Sun, Wenshou,&An, Zengjian.(2017).A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions.CATALYSIS COMMUNICATIONS,93,1-4. |
MLA | Xin, Hongchuan,et al."A green catalytic method for selective synthesis of iodophenols via aerobic oxyiodination under organic solvent-free conditions".CATALYSIS COMMUNICATIONS 93(2017):1-4. |
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