| High performance chiral separation materials based on chitosan bis(3,5-dimethylphenylcarbamate)-(alkyl urea)s | |
| Wang, Jing1; Xi, Jiang-Bo1; Chen, Wei1; Huang, Shao-Hua2; Bai, Zheng-Wu1 | |
| 2017-01-20 | |
| 发表期刊 | CARBOHYDRATE POLYMERS
 |
| 卷号 | 156页码:481-489 |
| 摘要 | Enantioseparation plays an important role for many fields and for pharmaceutical industry in particular. Chiral stationary phase (CSP) is the core of chiral liquid chromatography that effectively implements enantioseparation. In order to develop coated type CSPs with excellent enantioseparation capability and high tolerance against mobile phases, in this work, a series of chitosan bis(3,5-dimethylphenylcarbamate)(alkyl urea)s were synthesized, which were coated on 3-aminopropyl silica gel to afford new CSPs. Owing to strong hydrogen bonds formed among the synthesized derivatives, the supra-structure of the derivatives should be highly ordered. Hence, these CSPs could provide excellent separation capability and could tolerate common organic solvents that are usually prohibited for coated type CSPs of cellulose and amylose derivatives. Therefore the newly prepared CSPs exhibited promising prospects for enantioseparation of chiral compounds. (C) 2016 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Chitosan Derivatization Chiral Stationary Phase Enantioseparation High Performance Liquid Chromatography |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.carbpol.2016.09.047 |
| 关键词[WOS] | STATIONARY PHASES ; LIQUID-CHROMATOGRAPHY ; POLYSACCHARIDE DERIVATIVES ; SILICA-GEL ; ENANTIOSEPARATION CHARACTERISTICS ; PACKING MATERIALS ; AMYLOSE ; CELLULOSE ; ENANTIOMERS ; IMMOBILIZATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry ; Polymer Science |
| 项目资助者 | National Natural Science Foundation of China(51373127) |
| WOS类目 | Chemistry, Applied ; Chemistry, Organic ; Polymer Science |
| WOS记录号 | WOS:000388110900054 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/9100 |
| 专题 | 公共实验室 |
| 作者单位 | 1.Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430073, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jing,Xi, Jiang-Bo,Chen, Wei,et al. High performance chiral separation materials based on chitosan bis(3,5-dimethylphenylcarbamate)-(alkyl urea)s[J]. CARBOHYDRATE POLYMERS,2017,156:481-489. |
| APA | Wang, Jing,Xi, Jiang-Bo,Chen, Wei,Huang, Shao-Hua,&Bai, Zheng-Wu.(2017).High performance chiral separation materials based on chitosan bis(3,5-dimethylphenylcarbamate)-(alkyl urea)s.CARBOHYDRATE POLYMERS,156,481-489. |
| MLA | Wang, Jing,et al."High performance chiral separation materials based on chitosan bis(3,5-dimethylphenylcarbamate)-(alkyl urea)s".CARBOHYDRATE POLYMERS 156(2017):481-489. |
| 条目包含的文件 | 条目无相关文件。 | |||||
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论