A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties

doi:10.1039/c6ce01827k

QIBEBT-IR > 膜分离与催化研究组

	A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties
	Jiao, Chengli1 ; Jiang, Xia 2; Chu, Hailiang 3; Jiang, Heqing1 ; Sun, Lixian 3
	2016
发表期刊	CRYSTENGCOMM
卷号	18 期号:44 页码:8683-8687
摘要	A novel 3D mixed-valent Cu-I/Cu-II metal-organic framework has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, photoluminescence spectroscopy, thermal gravimetric analysis, and powder X-ray diffraction. The structure possesses a 3D open framework constructed from the linkages of 1D [Cu-I(4,4'-bipy)](n) chains with [Cu-II(oda)(2)](2-) cationic subunits. The chemical sensing properties of this MOF have been studied by the quartz crystal microbalance technique. The framework exhibits good selectivity and sensitivity to water with respect to other organic solvents in view of chemical sensing applications.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c6ce01827k
关键词[WOS]	COORDINATION POLYMER ; SOLVENT MOLECULES ; LIGAND ; LUMINESCENCE ; COMPLEXES ; CATALYSTS ; SORPTION ; SENSORS ; BINDING ; METHANE
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Crystallography
项目资助者	National Natural Science Foundation of China(21403267) ; Shandong Postdoctoral Innovation Program(201303065)
WOS类目	Chemistry, Multidisciplinary ; Crystallography
WOS记录号	WOS:000387975900018
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/9094
专题	膜分离与催化研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
推荐引用方式 GB/T 7714	Jiao, Chengli,Jiang, Xia,Chu, Hailiang,et al. A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties[J]. CRYSTENGCOMM,2016,18(44):8683-8687.
APA	Jiao, Chengli,Jiang, Xia,Chu, Hailiang,Jiang, Heqing,&Sun, Lixian.(2016).A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties.CRYSTENGCOMM,18(44),8683-8687.
MLA	Jiao, Chengli,et al."A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties".CRYSTENGCOMM 18.44(2016):8683-8687.