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Decarboxylative/Sonogashira-type cross-coupling using PdCl2(Cy*Phine)(2)
Yang, Yong1,3; Lim, Yee Hwee1; Robins, Edward G.2; Johannes, Charles W.1
2016
发表期刊RSC ADVANCES
卷号6期号:76页码:72810-72814
摘要The PdCl2(Cy*Phine)(2) precatalyst containing the meta-terarylphosphine ligand, Cy*Phine, can effectively mediate decarboxylative cross-coupling with a diverse range of (hetero-)aryl, aryl and alkyl chlorides including those with unprotected functionality. Using a facile and robust protocol, this process was extended to the first synthesis of symmetrical di(heteroaryl)alkynes via tandem Sonogashira/decarboxylative cross-coupling of heteroaryl chlorides and propiolic acid.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6ra12916a
关键词[WOS]ALKYNYL CARBOXYLIC-ACIDS ; ONE-POT SYNTHESIS ; ARYL CHLORIDES ; SONOGASHIRA REACTIONS ; TERMINAL ALKYNES ; PROPIOLIC ACID ; EFFICIENT ; DIARYLALKYNES ; HALIDES ; PRECATALYSTS
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者A*STAR Joint Council Office (JCO) ; Singapore 1st JCO Developmental Programme (DP)(JCO 1230400020) ; A*STAR Institute of Chemical and Engineering Sciences (ICES) ; A*STAR Singapore Bioimaging Consortium (SBIC)
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000381513300118
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8529
专题低碳催化转化研究组
作者单位1.ASTAR, ICES, Organ Chem, 8 Biomed Grove,Neuros 07-01, Singapore 138665, Singapore
2.ASTAR, Singapore Bioimaging Consortium SBIC, 11 Biopolis Way,Helios 01-02, Singapore 138667, Singapore
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China
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GB/T 7714
Yang, Yong,Lim, Yee Hwee,Robins, Edward G.,et al. Decarboxylative/Sonogashira-type cross-coupling using PdCl2(Cy*Phine)(2)[J]. RSC ADVANCES,2016,6(76):72810-72814.
APA Yang, Yong,Lim, Yee Hwee,Robins, Edward G.,&Johannes, Charles W..(2016).Decarboxylative/Sonogashira-type cross-coupling using PdCl2(Cy*Phine)(2).RSC ADVANCES,6(76),72810-72814.
MLA Yang, Yong,et al."Decarboxylative/Sonogashira-type cross-coupling using PdCl2(Cy*Phine)(2)".RSC ADVANCES 6.76(2016):72810-72814.
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