Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts | |
Chen, Dawei1,2; Liang, Fengbing1; Feng, Dexin1; Du, Fanglin2; Zhao, Guang1; Liu, Huizhou1; Xian, Mo1 | |
2016-09-05 | |
发表期刊 | CATALYSIS COMMUNICATIONS |
卷号 | 84页码:159-162 |
摘要 | Bifunctional lignosulfonate-based catalysts (LS-M) with Lewis acid and basic sites were designed and prepared by immobilizing metal ions on lignosulfonate. Catalysts were characterized by XRD, XPS, SEM, EDX, TEM, TGA, NH3/CO2-TPD and FTIR, and applied in transformation of carbohydrate biomass to furan derivatives (HMF/furfural) in mixed water/THF systems. With LS-Cr as catalyst, the optimized yields of HMF from cellulose, glucose and mannose were 46.3%, 60.4% and 68.8%, and that of furfural from xylan, xylose and arabinose were 40.2%, 73.1% and 51.6%, respectively. The catalysts could be easily recycled with negligible wastage of the active metal ions. (C) 2016 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Lignocellulose Cellulose Xylan Hmf Furfural |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.catcom.2016.06.012 |
关键词[WOS] | IONIC LIQUIDS ; ACID ; CONVERSION ; LIGNIN ; ISOMERIZATION ; CHEMICALS ; FRUCTOSE ; GLUCOSE ; XYLOSE ; WATER |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
项目资助者 | National 863 Program of China(SS2013AA050703-2) ; Taishan Scholars Climbing Program of Shandong(tspd20150210) |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000381534300036 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/8502 |
专题 | 生物基材料组群 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol China, CAS Key Lab Biobased Mat, Beijing 100864, Peoples R China 2.Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Nanostruct Mat, Qingdao 266042, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Dawei,Liang, Fengbing,Feng, Dexin,et al. Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts[J]. CATALYSIS COMMUNICATIONS,2016,84:159-162. |
APA | Chen, Dawei.,Liang, Fengbing.,Feng, Dexin.,Du, Fanglin.,Zhao, Guang.,...&Xian, Mo.(2016).Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts.CATALYSIS COMMUNICATIONS,84,159-162. |
MLA | Chen, Dawei,et al."Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts".CATALYSIS COMMUNICATIONS 84(2016):159-162. |
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