Structure of 2D Graphdiyne and Its Application in Energy Fields

doi:10.3866/PKU.WHXB201605035

QIBEBT-IR > 仿生与固态能源系统研究组

	Structure of 2D Graphdiyne and Its Application in Energy Fields
	Huang Chang-Shui 1; Li Yu-Liang 2
	2016-06-15
发表期刊	ACTA PHYSICO-CHIMICA SINICA
卷号	32 期号:6 页码:1314-1329
摘要	This paper focuses on application of graphdiyne (GDY) in both energy storage and conversion fields, including the most recent theoretical and experimental progress. The unique three-dimensional pore structure formed by stacking of the GDY layer, make it possess the natural advantage which can be applied to lithium storage and hydrogen storage. Because of its lithium storage ability, GDY can be used in energy storage devices, such as lithium ion batteries and lithium ion capacitors. While with the hydrogen storage property, GDY can be used as a hydrogen storage material in fuel cells. By doping method, the performance of GDY for lithium and hydrogen storage can be further improved. Owing to acetylene units composed of sp hybridized carbon atoms and benzene rings composed of sp(2) hybridized carbon atoms, GDY possesses multiple conjugated electronic structures. Thus, its band gap can be regulated through many ways accompanied with existence of Dirac cones. This property means that GDY can not only be used as a high-activity non-metal catalyst in place of noble metal catalysts in photocatalysis, but it also plays a promotional role in the hole transport layer and electron transport layer of solar cells. All of the reported results including theoretical and experimental data reviewed here, show the great potential of GDY in energy field applications.
文章类型	Review
关键词	Graphdiyne Lithium Storage Hydrogen Storage Catalysis Solar Cell
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.3866/PKU.WHXB201605035
关键词[WOS]	OXYGEN REDUCTION REACTIONS ; LI-DECORATED GRAPHYNE ; CARBON NANOTUBES ; ELECTRONIC-STRUCTURE ; SOLAR-CELLS ; THEORETICAL PREDICTIONS ; 2-DIMENSIONAL CARBON ; CONJUGATED POLYMERS ; CARRIER MOBILITY ; STORAGE CAPACITY
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	National Basic Research 973 Program of China(2012CB932901) ; "100 Talents" Program of the Chinese Academy of Sciences
WOS类目	Chemistry, Physical
WOS记录号	WOS:000378824300002
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8357
专题	仿生与固态能源系统研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Huang Chang-Shui,Li Yu-Liang. Structure of 2D Graphdiyne and Its Application in Energy Fields[J]. ACTA PHYSICO-CHIMICA SINICA,2016,32(6):1314-1329.
APA	Huang Chang-Shui,&Li Yu-Liang.(2016).Structure of 2D Graphdiyne and Its Application in Energy Fields.ACTA PHYSICO-CHIMICA SINICA,32(6),1314-1329.
MLA	Huang Chang-Shui,et al."Structure of 2D Graphdiyne and Its Application in Energy Fields".ACTA PHYSICO-CHIMICA SINICA 32.6(2016):1314-1329.