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Influence of a pi-bridge dependent molecular configuration on the optical and electrical characteristics of organic solar cells
Wang, Ting1; Han, Liangliang1; Wei, Huan1; Zhu, Dangqiang1; Bao, Xichang1; Qiao, Shanlin1; Sun, Weizhi1; Chen, Weichao1; Yang, Renqiang1,2
2016-06-14
发表期刊JOURNAL OF MATERIALS CHEMISTRY A
卷号4期号:22页码:8784-8792
摘要A new solution processed A-pi-D-pi-A type small molecule denoted as DCATT-L has been synthesized as a donor for bulk-heterojunction (BHJ) solar cells. Compared with its isomer DCATT, reported in our previous work, DCATT-L possesses the same building blocks, but different pi-bridge configurations and hence different backbone configurations. Changing the pi-bridge with delicate designs, the absorption coefficient is increased significantly and the highest occupied molecular orbital (HOMO) energy level is decreased by 0.1 eV. The excellent optical and electrical properties of DCATT-L guarantee the enhancement of power conversion efficiency (PCE) to 7.72%, compared with that of DCATT (5.20%), with simultaneously increasing open-circuit voltage, short-circuit current density and fill factor.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1039/c6ta02977a
关键词[WOS]POWER CONVERSION EFFICIENCY ; PROCESSED SMALL-MOLECULE ; PORPHYRIN SMALL-MOLECULE ; OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PROPERTIES ; BENZODITHIOPHENE UNIT ; CONJUGATED POLYMERS ; END-GROUPS ; PERFORMANCE ; DONOR
收录类别SCI
语种英语
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
项目资助者National Natural Science Foundation of China(21274161 ; Ministry of Science and Technology of China(2014CB643501 ; Shandong Provincial Natural Science Foundation(ZR2015EQ002) ; Qingdao Institute of Bioenergy and Bioprocess Technology Director Innovation Foundation for Young Scientists(QIBEBT-DIFYS-201507) ; 51303197 ; 2010DFA52310) ; 51503219 ; 51573205 ; 61107090 ; 61405209)
WOS类目Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号WOS:000378583200034
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8356
专题先进有机功能材料研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
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Wang, Ting,Han, Liangliang,Wei, Huan,et al. Influence of a pi-bridge dependent molecular configuration on the optical and electrical characteristics of organic solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(22):8784-8792.
APA Wang, Ting.,Han, Liangliang.,Wei, Huan.,Zhu, Dangqiang.,Bao, Xichang.,...&Yang, Renqiang.(2016).Influence of a pi-bridge dependent molecular configuration on the optical and electrical characteristics of organic solar cells.JOURNAL OF MATERIALS CHEMISTRY A,4(22),8784-8792.
MLA Wang, Ting,et al."Influence of a pi-bridge dependent molecular configuration on the optical and electrical characteristics of organic solar cells".JOURNAL OF MATERIALS CHEMISTRY A 4.22(2016):8784-8792.
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