Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water

doi:10.1038/srep28558

QIBEBT-IR > 绿色化学催化研究组

	Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water
	Chen, Xiufang; Zhang, Ligang; Zhang, Bo; Guo, Xingcui; Mu, Xindong
	2016-06-22
发表期刊	SCIENTIFIC REPORTS
卷号	6
摘要	Graphitic carbon nitride nanosheets were investigated for developing effective Pt catalyst supports for selective hydrogenation of furfural to furfuryl alcohol in water. The nanosheets with an average thickness of about 3 nm were synthesized by a simple and green method through thermal oxidation etching of bulk g-C3N4 in air. Combined with the unique feature of nitrogen richness and locally conjugated structure, the g-C3N4 nanosheets with a high surface area of 142 m(2) g(-1) were demonstrated to be an excellent supports for loading small-size Pt nanoparticles. Superior furfural hydrogenation activity in water with complete conversion of furfural and high selectivity of furfuryl alcohol (> 99%) was observed for g-C3N4 nanosheets supported Pt catalysts. The large specific surface area, uniform dispersion of Pt nanoparticles and the stronger furfural adsorption ability of nanosheets contributed to the considerable catalytic performance. The reusability tests showed that the novel Pt catalyst could maintain high activity and stability in the furfural hydrogenation reaction.
文章类型	Article
WOS标题词	Science & Technology
DOI	10.1038/srep28558
关键词[WOS]	CARBON NITRIDE POLYMERS ; VISIBLE-LIGHT ; LIQUID-PHASE ; METAL NANOPARTICLES ; MILD CONDITIONS ; OXIDATION ; REDUCTION ; QUINOLINE ; CHEMICALS ; BIOMASS
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics
项目资助者	National Natural Science Foundation of China(21201174 ; Qingdao Applied Basic Research Project(14-2-4-21-jch) ; Shandong Provincial Natural Science Foundation for Distinguished Young Scholar, China(JQ201305) ; 21433001 ; 31370563)
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000378249900001
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8335
专题	绿色化学催化研究组
作者单位	Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Chen, Xiufang,Zhang, Ligang,Zhang, Bo,et al. Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water[J]. SCIENTIFIC REPORTS,2016,6.
APA	Chen, Xiufang,Zhang, Ligang,Zhang, Bo,Guo, Xingcui,&Mu, Xindong.(2016).Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water.SCIENTIFIC REPORTS,6.
MLA	Chen, Xiufang,et al."Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water".SCIENTIFIC REPORTS 6(2016).