Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries | |
Ma, Jun1; Hu, Pu1; Cui, Guanglei1; Chen, Liquan1,2 | |
2016-06-14 | |
发表期刊 | CHEMISTRY OF MATERIALS |
卷号 | 28期号:11页码:3578-3606 |
摘要 | Spinel LiNi0.5Mn1.5O4 with high operating voltage (similar to 4.7 V vs Li/Li+), high theoretical capacity of 148 mAh g(-1), fast lithium ion diffusion kinetics, and potentially low cost is the most potential candidate material for high energy density LIBs used in plug-in hybrid electric vehicles and pure electric vehicles. However, the high operating voltage of LiNi0.5Mn1.5O4 challenges the electrochemical stability of other components in the batteries and induce diverse interfacial side reactions, leading to irreversible capacity loss, poor cycling performance, and safety issues, especially at the elevated temperatures. Thus, a basic understanding of the intrinsic surface properties of LiNi0.5Mn1.5O4 and the mechanism of interfacial interactions between each component in the electrochemical system is a critical requirement for developing substantial enhancements of LiNi0.5Mn1.5O4-based batteries. In this review, we summarize the surface/interface reactions and challenges in the whole cell system of LiNi0.5Mn1.5O4-based LIBs. Perspectives and strategies for LiNi0.5Mn1.5O4-based high energy density batteries used in PHEV/EVs are also proposed at last. |
文章类型 | Review |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1021/acs.chemmater.6b00948 |
关键词[WOS] | HIGH-VOLTAGE SPINEL ; GEL POLYMER ELECTROLYTE ; ALKYLCARBONATE-BASED ELECTROLYTES ; HIGH-TEMPERATURE PERFORMANCE ; SULFONE-BASED ELECTROLYTES ; RECHARGEABLE LI BATTERIES ; CHARGE-DISCHARGE BEHAVIOR ; HIGH-RATE CAPABILITY ; LONG-CYCLE-LIFE ; 5 V CATHODE |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Materials Science |
项目资助者 | CAS-QIBEBT Director Innovation Foundation ; Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation of China(51502319) ; Shandong Provincial Natural Science Foundation(ZR2015QZ01) |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000378016400005 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/8325 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioprocess Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Jun,Hu, Pu,Cui, Guanglei,et al. Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries[J]. CHEMISTRY OF MATERIALS,2016,28(11):3578-3606. |
APA | Ma, Jun,Hu, Pu,Cui, Guanglei,&Chen, Liquan.(2016).Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries.CHEMISTRY OF MATERIALS,28(11),3578-3606. |
MLA | Ma, Jun,et al."Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries".CHEMISTRY OF MATERIALS 28.11(2016):3578-3606. |
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