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Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries
Ma, Jun1; Hu, Pu1; Cui, Guanglei1; Chen, Liquan1,2
2016-06-14
发表期刊CHEMISTRY OF MATERIALS
卷号28期号:11页码:3578-3606
摘要Spinel LiNi0.5Mn1.5O4 with high operating voltage (similar to 4.7 V vs Li/Li+), high theoretical capacity of 148 mAh g(-1), fast lithium ion diffusion kinetics, and potentially low cost is the most potential candidate material for high energy density LIBs used in plug-in hybrid electric vehicles and pure electric vehicles. However, the high operating voltage of LiNi0.5Mn1.5O4 challenges the electrochemical stability of other components in the batteries and induce diverse interfacial side reactions, leading to irreversible capacity loss, poor cycling performance, and safety issues, especially at the elevated temperatures. Thus, a basic understanding of the intrinsic surface properties of LiNi0.5Mn1.5O4 and the mechanism of interfacial interactions between each component in the electrochemical system is a critical requirement for developing substantial enhancements of LiNi0.5Mn1.5O4-based batteries. In this review, we summarize the surface/interface reactions and challenges in the whole cell system of LiNi0.5Mn1.5O4-based LIBs. Perspectives and strategies for LiNi0.5Mn1.5O4-based high energy density batteries used in PHEV/EVs are also proposed at last.
文章类型Review
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1021/acs.chemmater.6b00948
关键词[WOS]HIGH-VOLTAGE SPINEL ; GEL POLYMER ELECTROLYTE ; ALKYLCARBONATE-BASED ELECTROLYTES ; HIGH-TEMPERATURE PERFORMANCE ; SULFONE-BASED ELECTROLYTES ; RECHARGEABLE LI BATTERIES ; CHARGE-DISCHARGE BEHAVIOR ; HIGH-RATE CAPABILITY ; LONG-CYCLE-LIFE ; 5 V CATHODE
收录类别SCI
语种英语
WOS研究方向Chemistry ; Materials Science
项目资助者CAS-QIBEBT Director Innovation Foundation ; Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation of China(51502319) ; Shandong Provincial Natural Science Foundation(ZR2015QZ01)
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号WOS:000378016400005
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8325
专题仿生与固态能源系统研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioprocess Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China
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Ma, Jun,Hu, Pu,Cui, Guanglei,et al. Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries[J]. CHEMISTRY OF MATERIALS,2016,28(11):3578-3606.
APA Ma, Jun,Hu, Pu,Cui, Guanglei,&Chen, Liquan.(2016).Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries.CHEMISTRY OF MATERIALS,28(11),3578-3606.
MLA Ma, Jun,et al."Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries".CHEMISTRY OF MATERIALS 28.11(2016):3578-3606.
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